锂离子电池隔膜研究进展 Текст научной статьи по специальности «Технологии материалов»

V. Технологии, материаловедение,

энергоэффективность

For citation: Liu Teng, Zhou Shi, Wang Jian. Research progress of lithium-ion battery separator //

URL: http://rectors.altstu.ru/ru/periodical/archiv/2022/1/articles/5_1.pdf DOI: 10.25712/ASTU.2410-485X.2022.01.010 EDN: https://elibrary.ru/ixnkpn

Y^K 621.355

Research progress of lithium-ion battery separator

Liu Teng1, Zhou Shi1, Wang Jian1

1 Hubei Digital Textile Equipment Key Laboratory, School of Mechanical Engineering and Automation,

Wuhan Textile University, Wuhan 430073, China E-mail: 651672560@qq.com

0

immmx é

[1]. rnsOTifê^âtœ^,

unworn»!, «^m^r^tra^Mi 10%-

14%, ÎM^ÎT^«^^. ^inm^

«l^ttm [2].

i.i mm^&mnxftmm

^Miim^m^j, ^x^mœ^w, xm Li+ Em,

i. ft^Mj^Rft^, Li+ gm^mt

M, xm^m^mmmmm&mxm, ^f^^^fMxm^^^i^

^ [3]. Mm^^mis^x^^i^s 1 m^.

i*i _(Я)_1

№

&mmJÎF ft

Li+ Ll

-a 4 Li*

r_о ■ ■ ►

Lifl

4 I I i +

rn i [4]

Fig. 1. Schematic diagram of the composition and working principle of a lithium-ion battery [4]

1.2 mmttmmrnM&toM*

usabc ^ 2017 ^

1 rn^.

Table 1. Requirements and goals for separators for lithium-ion batteries [5]

\STM U2I0J

^^ ^lUurkflflJ я спг71 <11 (¿A*Sf<25(Bfl-<!!!l иЯМЧЫ^ЗВ

МясМиНт

Sfàtt шмашдшг

РД7 Ц&Ц- M

<in AS'ÏW Г 128-W

iftfiitHiMi-^-- <5 AS1M0 1

и mufci ttrau

i 1 UUOpai il] !я |Г- ^ V^i <-1 AfiT^M D

lOStS

5.(1

^JtfiÉUïnC

<50 —

2 «ШШ^

2.1 тшммлшшм

шшшшшш (pe) тмш (pp) ^rn ^шж-^шш. тшмш,

^МЖ^Ш^НМ PP/PE/PP М^Ш [6]. Ma [7] (pp) ШШ^ШФ, Й^ШШЙ A1PO4, ЩШ^Й-ЛШЙ

A1PO4 Ш^ШФЖШ^, ШД

Liu [8] ЖЙ»

йй (pp) SiO2/PAM, РМЙФШШЙШ^, pp

ШШЙ 150оС Т 30min ЙЙМ^^Ш 70% ^ 12%, >АШШЙ7Ш1ЙШ1№

2.2 мшшт

Yanilmaz [9] # АМЖ^Й7 ^ Н «Ш Й Ш ¥ SM^M ¥ Ш (PMMA)/ШШ (PAN) ШШ, ^ттШШЛШШ'Штьт, Ж^ PMMA/PAN мйй^^щшш, ^М^ЙЖ

-^И^ИЙ^Ш^ЖМ. ШЖ^ШЙ^Й PMMA/PAN ШШМ^ Li/LiFePO4 Gong [10] #

160ОС Ш

НЙ PPESK / PVDF ^

^шшшйшшжш, xie [ii] ^лжадш^шшт ад

Ш. ШШЙ^ШШт

[12] (nmp) ^

ЖШх^ШШМ^ЙШШШ. й ЖШШ&ШШ, М^М^Ш

Cho [13] »^ШШЙМШ N-SiO2

3

3.1 тшяшхя

хшхшшшшш (mscs),

00PU

т

шшш, &мштш№тхштштж ££

4У

ж^м^ттш [14]. шшххм^т^, тжшш-ш'м и, штттмммж^шттйп^ тт^шттшття

ШШ'Ш* [15].

ш 2 штшшхгшм [16]

Fig. 2. Process flow of wet/dry diaphragm [16]

3.2 ШШХ2

ШШШ, &ШШШ, ?U5/J\ ВШХ ШЫШШ& [17].

ffl з ШШШЛШШШ [18]

Fig. 3. The working principle of electrospinning [18]

3.3 Ш'ЫШМХЯ

РЙШп^МШ [19].

Fig. 4. The working principle of centrifugal spinning [19]

5

х^^ййшйшшм^т Шй

1] тшх х®^, ш, ^/\штжх^штттшшхжт%

ЙМ [J]. 2018, 32(23):4051-4060.

2] хш, тм, птщ, ^к^, пш, шя шш.

МДЙШМ [J]. Х^ШЙ, 2019, 41(02):14-20.

3] mm, мфж, мжм, ш*/К хш, шшш. ежх^шиша^шмм

[J]. &МЯШШЩ, 2021, 28(02):37-58.

4] rnrnrn, хм, ^шж, хшш. [j]. мххшш,

2017(06):59-67.

5] ймм, пш, мшф. шш&мшт&шшшштжш%ш [J]. ш

ШХ, 2021, 45(08):1087-1090+1099.

6] ШШ, ШШШ, ХШФ. Шй^в^Х^МйШШ^йМ [J]. , 2020,

35(02):24-29.

7] Shasha Ma, Hai Lin, Luyi Yang, Qingsong Tong, Feng Pan, Jingzheng Weng, Sining Zheng. High thermal stability and low impedance polypropylene separator coated with aluminum phosphate [J]. Electrochimica Acta, 2019, 320(C).

8] Meihua Liu, Pengpeng Zhang, Liting Gou, Zeyun Hou, Bin Huang. Enhancement on the thermostability and wettability of lithium-ion batteries separator via surface chemical modification [J]. Materials Letters, 2017, 208.

9] Meltem Yanilmaz, Xiangwu Zhang. Polymethylmethacrylate/Polyacrylonitrile Membranes via Centrifugal Spinning as Separator in Li-Ion Batteries [J]. Polymers, 2015, 7(4).

10] Wenzheng Gong, Xinyu Wang, Zheng Li, Junfeng Gu, Shilun Ruan, Changyu Shen. A high-strength PPESK/PVDF fibrous membrane prepared by coaxial electrospinning for lithium-ion battery separator [J]. High Performance Polymers, 2019, 31(8).

11] Jian-De Xie, Chun-Chieh Fu, Chun-Chieh Liao, Ruey-Shin Juang, Yasser Ashraf Gandomi. Alumina nanocoating of polymer separators for enhanced thermal and electrochemical performance of Li-ion batteries [J]. Asia-Pacific Journal of Chemical Engineering, 2019, 14(4).

12] xrn, mm, шда$, -m дхвжх^ш^ш^лм^шш j]. шшх, 2015,

39(06):1194-1197.

13] Jinhyun Cho, Yun-Chae Jung, Yun Sung Lee, Dong-Won Kim. High performance separator coated with amino-functionalized SiO2 particles for safety enhanced lithium-ion batteries [J]. Journal of Membrane Science, 2017, 535.

14] ьж^. [D]. штхш, 2014.

15] пх-, тяп, j]. гшх, 2021,

48(12):95-97.

16] тш, м, тж, тхй, тт. [j]. шшх, 2021,

45(08):983-985+1011.

17] «м, пх, шшт, j фшшй, 2022,

41(02):104-114.

18] шхх, mm. [j]. rnrnun, 2018, 51(11*7-13.

19] тЩ, ^ШМ, ШШ М'ЫШШХШЖШ [J]. 2021, 39(04):1-5.