TECHNOLOGY OF MANUFACTURING SAMPLES FROM POLYMER COMPOSITE MATERIALS Текст научной статьи по специальности «Технологии материалов»

Vestnik of Astrakhan State Technical University. Series: Marine engineering and technologies. 2023. N. 3 ISSN 2073-1574 (Print), ISSN 2225-0352 (Online)

Shipbuilding, ship repair andfleet operation

Original article UDC 629.12

https://doi.org/10.24143/2073-1574-2023-3-19-26 EDN WRETKT

Technology of manufacturing samples from polymer composite materials

Maksim A. Meleshin1^, Ali Salamekh2, Victor A. Mamontov3

1Volga State University of Water Transport, Nizhny Novgorod, Russia, [email protected]

2Caspian Institute of Sea and River Transport after General-Admiral F. M. Apraksin, branch of Volga State University of Water Transport, Astrakhan, Russia

3Astrakhan State Technical University, Astrakhan, Russia

Abstract. The article considers the materials, composition and methods of manufacturing samples from polymer composite materials (PCM). There is presented the method of testing samples of PCM for mechanical properties. For testing, plates were made from which samples from PCM were cut, based on glass roving, glass wool and polyester resin with the addition of a hardener. Using mechanical tests, the influence of the quantitative ratio of layers of glass wool and roving fiberglass has been determined when testing samples for three-point bending, stretching and compression. A scheme of structural reinforcement of PCM plates is given, graphs of the average values of breaking loads and ultimate strengths when testing samples for three-point bending, dependences of average values of breaking loads and ultimate strengths when testing samples for tension and compression are illustrated. Comparative analysis of the average values of the tensile strength of the samples during the compression test has been carried out. As a result of processing the data obtained during the study, it was found that with an increased number of layers of roving glass in the PCM composition increases the destructive load and tensile strength, compression, but the values of the applied load of PCM samples decrease during three-point bending tests. The experimental data obtained from the test results of PCM samples are the main indicators of the mechanical properties of PCM with various reinforcement schemes for their use in ship hull structures, in particular as a material for ship tanks.

Keywords: shipbuilding, polymer composite materials, glass wool, roving glass, polyester resin, mechanical properties, ultimate stress, applied load, destructive load

For citation: Meleshin M. A., Salamekh Ali, Mamontov V. A. Technology of manufacturing samples from polymer composite materials. Vestnik of Astrakhan State Technical University. Series: Marine Engineering and Technologies. 2023;3:19-26. (In Russ.). https://doi.org/10.24143/2073-1574-2023-3-19-26. EDN WRETKT.

Научная статья

Технология изготовления образцов из полимерных композиционных материалов

Максим Алексеевич Мелешин1ш, Али Саламех 2, Виктор Андреевич Мамонтов 3

1Волжский государственный университет водного транспорта, Нижний Новгород, Россия, [email protected]

2Каспийский институт морского и речного транспорта имени генерал-адмирала Федора Матвеевича Апраксина, филиал Волжского государственного университета водного транспорта, Астрахань, Россия

3Астраханский государственный технический университет, Астрахань, Россия

Аннотация. Рассматриваются применяемые материалы, состав и методы изготовления образцов из полимерных композиционных материалов (ПКМ). Приведена методика испытаний образцов из ПКМ на механические свойства. Для испытаний были изготовлены пластины, из которых были нарезаны образцы из ПКМ, на основе ровенговой стеклоткани, стекломата и полиэфирной смолы с добавлением отвердителя. С помощью механи-

© Meleshin M. A., Salamekh Ali, Mamontov V. A., 2023

Вестник Астраханского государственного технического университета.

Серия: Морская техника и технология. 2023. № 3 ISSN 2073-1574 (Print), ISSN 2225-0352 (Online)

Судостроение, судоремонт и эксплуатация флота

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ческих испытаний определено влияние количественного соотношения слоев стекломата и ровинговой стеклоткани при испытании образцов на изгиб, растяжение и сжатие. Приведена схема структурного армирования пластин из ПКМ, проиллюстрированы графики зависимости средних значений разрушающих нагрузок и пределов прочности при испытании образцов на трехточечный изгиб, зависимости средних значений разрушающих нагрузок и пределов прочности при испытании образцов на растяжение, а также на сжатие. Проведен сравнительный анализ средних значений пределов прочности образцов при испытании на сжатие. В процессе анализа полученных данных после испытания образцов установлено, что с увеличением количественного соотношения слоев ровинговой стеклоткани в составе ПКМ увеличивается разрушающая нагрузка и предел прочности на растяжение, сжатие, но уменьшаются показатели значений прилагаемой нагрузки образцов из ПКМ при испытаниях на изгиб. Полученные экспериментальные данные результатов испытаний образцов из ПКМ являются основными показателями механических свойств ПКМ при различных схемах армирования их применения в судовых корпусных конструкциях, в частности как материал судовых цистерн.

Ключевые слова: судостроение, полимерные композиционные материалы, стекломат, ровинговая стеклоткань, полиэфирная смола, механические свойства, предел прочности, прилагаемая нагрузка, разрушающая нагрузка

Для цитирования: Мелешин М. А., Саламех Али, Мамонтов В. А. Технология изготовления образцов из полимерных композиционных материалов // Вестник Астраханского государственного технического университета. Серия: Морская техника и технология. 2023. № 3. С. 19-26. https://doi.org/10.24143/2073-1574-2023-3-19-26. EDN WRETKT.

Introduction

The development of modern technologies requires new design solutions. One of the most interesting and promising solutions is composite materials (CM). Polymer composite materials (PCM) have become increasingly used in modern industrial engineering; they are used when no other material meets the growing pace and requirements of future technologies. Application of PCM is one of the important priorities of the formation and development of new shipbuilding [1].

Currently, PCM are replacing traditional structural materials such as metal, aluminum alloys, wood and reinforced concrete. The possibilities of PCM are limitless due to the variety of both polymers and fillers, a variety of compounds and methods of their modification.

The unique properties of PCM are corrosion resistance under different climatic conditions, non-magnetism, high strength and low specific gravity

Different technologies are used for manufacturing PCM: contact molding, manual molding, closed vacuum molding, spraying, vacuum infusion, injection. Regardless of the technology used, the composition of PCM includes reinforcing and binding materials. As a reinforcing material in the manufacture of PCM, fibers from standard alkali-free aluminoborosilicate glass of the E brand or high-modulus magnesia-aluminosilicate glass of the VMP brand are mainly used [2].

The purpose of the study is to determine the influence of the location of reinforcing layers (glass wool and roving glass) on the values of tensile strength, compression and three-point bending. The object of the study is six layered samples of CM with the use of glass fabrics and with a different method of arrangement of reinforcing materials and a different quantitative ratio of layers.

Method of manufacturing PCM samples for testing mechanical properties

The new edition of the Russian maritime register

of shipping (RMRS) rules states that PCM is allowed to be used in ship structures based on carbon, glass and aramid fibers as reinforcing elements, and epoxy, vinyl ether and polyester resins with the addition of a hardener are used as a binder.

In the process of manufacturing PCM samples, two schemes of laying CM were selected.

Two batches of plates (I and II) were made differently laying the glass fabrics. The composition of the PCM plates includes the following elements: EMC emulsion glass-600-1250- E, roving fabric EWR 560, polyester resin Yarkopol-110, and hardener methyl ethyl ketone peroxide (BUTANOX M-50).

The plates are manufactured by contact molding with manual laying on a matrix with dimensions of 1000^1000 mm, due to which the samples will turn out to be 600^600 mm in size.

The plates consist of six layers of reinforcing fiberglass, differ from each other only in the quantitative ratio of glass wool and roving fiberglass. The schematic diagram of the reinforcement of PCM plates is shown in Fig. 1. Table 1 shows the structural filling of PCM plates with a different formation scheme.

Fig. 1. Scheme of structural reinforcement of PCM plates

Vestnik of Astrakhan State Technical University. Series: Marine engineering and technologies. 2023. N. 3 ISSN 2073-1574 (Print), ISSN 2225-0352 (Online)

Shipbuilding, ship repair andfleet operation

The following patterns were selected for the preparation of the binder (polyester resin):

- 350 ml of polyester resin is consumed for each layer of reinforcing fiberglass (glass wool and roving glass);

- the curing process of PCM plates is carried out using a hardener methyl ethyl ketone peroxide (BU-TANOX M-50) with a dosage ratio of 1 ml of hardener per 100 ml of polyester resin for all types of plates;

- the main indicators of the air conditioning atmosphere for all types of plates are the same and amount to 15 hours at an ambient temperature of 23°C and humidity of 50% [3].

After making the plates, they must be rolled with a center roller along and across the direction of the fibers to remove air from under the layers and evenly distribute the resin, after which the plates are left for 36 hours until completely dry under normal temperature conditions. After complete drying of the plates, mechanical treatment of the end surfaces is performed to remove excess fiberglass with resin.

For testing, samples are cut from sheet material, using a milling machine and a disk with a sawtooth edge made of hardened steel [4].

Tests of samples from PCM in order to determine their mechanical characteristics were carried out on certified testing machines at the Department of Ship-Mechanical Disciplines of the Caspian Institute of Marine and River Transport named after General-Admiral F. M. Apraksin.

Testing samples for three-point bending

Test samples are made according to the normative technical documentation. Testing PCM samples for static bending is carried out according to GOST 46482014, samples are made of rectangular shape with dimensions of length and width 200*20 mm (Fig. 2) [5].

According to the average thickness of the samples, the distance between the supports is determined by the formula L = (16 ± 1)h. The test samples are placed on supports and subjected to three-point bending at a constant speed until complete destruction, while measuring the destructive load applied to the sample. The recommended loading speed is 10 mm/min, this is due to the fact that PCM is a material that, when destroyed, does not show bending stress at maximum load (Fig. 3). The bending strength of PCM is determined by the formula

where Fmax - applied load, N; L - distance between the supports, mm; b - width of the sample, mm; h - thickness of the sample, mm.

mt m m.b t. . a

MM,

Fig. 2. Samples for testing three-point bending

The distance between the supports is determined by the formula

L = (16 ± 1)h.

Fig. 3. Testing PCM samples on the R-5 machine for a three-point bend

Table 1 l

Reinforcement structure of manufactured plates

Plate Total number of layers Number of layers of roving glass Number of layers of glass wool

I reinforcement scheme 6 2 4

II reinforcement scheme 6 4 2

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Серия: Морская техника и технология. 2023. № 3 ISSN 2073-1574 (Print), ISSN 2225-0352 (Online)

Судостроение, судоремонт и эксплуатация флота

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Comparison of the results of PCM tests for three-point bending shows that the (Table 2) average applied load of the samples of the I reinforcement scheme (Fig. 4) is greater than that of the samples of the II

reinforcement scheme, but the average tensile strength of the samples of the II reinforcement scheme is higher (Fig. 5) than that of the samples of the I reinforcement scheme.

Table 2

Test results of samples for three-point bending

Sample Number Reinforcement scheme

I II

Fmax, kgp o, MPa Fmax, kgp o, MPa

1 80 158 55 166

2 77 164 65 165

3 80 154 70 179

4 90 164 80 196

5 80 161 80 177

Average values 81.4 160.2 70 176.6

Fig. 4. Graph of the dependence of the average values of destructive loads when testing samples for three-point bending

Tensile testing PCM samples

Testing samples for tensile strength is carried out in accordance with GOST 11261-17, samples must be made of a flat shape with a length of more than 250 mm, a head width of 25 mm and a thickness of at least 2 mm. At least five samples are used for testing isotropic materials, and at least five samples are used for testing anisotropic materials, cut in the places and directions specified in the regulatory document or technical documentation for the material or agreed between the interested parties (Fig. 6) [6]:

Fm

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A '

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where Fmax - destructive load, N; A = bh - cross-sectional area of the sample, mm2.

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Reinforcement schemes

Fig. 5. Graph of dependence of the average values of the tensile strength when testing samples for three-point bending

Fig. 6. PCM samples for tensile testing

The test samples are stretched along the axis at a constant speed of 5 mm/min; during the stretching process, the load sustained by the sample is measured, the destructive load and the tensile strength are determined (Fig. 7).

Vestnik of Astrakhan State Technical University. Series: Marine engineering and technologies. 2023. N. 3 ISSN 2073-1574 (Print), ISSN 2225-0352 (Online)

Shipbuilding, ship repair andfleet operation

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Fig. 7. Tensile testing PCM samples on the R-5 machine

A comparative analysis of the average values of the test results of the samples from the PCM tensile showed (Table 3) that the destructive load and tensile strength

of the samples of the II reinforcement (Fig. 8, 9) scheme is an order of magnitude higher than that of the samples of the I reinforcement scheme.

Table 3

Results of tensile testing of PCM samples

Sample Number Reinforcement scheme

I II

Fmax, kgp o, MPa Fmax, kgp o, MPa

1 1480 95 2150 177

2 2650 177 2210 182

3 2150 151 2125 181

4 2580 167 2250 191

5 1800 114 220 188

Average values 2132 140.8 2187 183.8

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Fig. 8. Graph of dependence of the average values of destructive loads during tensile testing of samples

Fig. 9. Graph of dependence of the average values of the tensile strength during the tensile testing of samples

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Судостроение, судоремонт и эксплуатация флота

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Compression testing of PCM samples

Compression test samples are manufactured, according to GOST 4651-2014 (Fig. 10). The manufactured samples have a square shape with dimensions of 10x10 mm and a thickness of at least 4 mm [7].

compressive strength of PCM samples is determined by the formula (1).

Fig. 10. PCM samples for compression tests

The test sample is compressed along its axis at a constant speed until it collapses or until the load decreases. The load applied to the sample is measured during the entire test process.

Polymer composite materials samples are installed in the center of the support platforms of the testing machine. During the testing process, it is recommended to use a thin sheet of sandpaper between the surfaces of the samples so that the samples do not slip on the support pads. The test samples are loaded by compression force (Fig. 11) perpendicular to the plane of laying the reinforcing layers on the R-5 testing machine with a recommended loading speed of 1 mm/min. The

Fig. 11. Compression testing PCM samples on the R-5 machine

A comparison of the average values of PCM samples for the destructive compression load showed (Table 4) that the destructive load and the tensile strength of the samples of the II reinforcement scheme (Fig. 12, 13) are an order of magnitude higher than the samples of the I reinforcement scheme.

Table 4

Results of compression testing of samples

Sample Number Reinforcement scheme

I II

Fmax, kgp o, MPa Fmax, kgp o, MPa

1 2500 510 2950 592

2 2570 436 4100 902

3 2650 430 2650 492

4 2900 508 3070 616

5 2860 476 3400 631

Average values 2696 472 3234 646.6

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Shipbuilding, ship repair andfleet operation

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Fig. 12. Graph of dependence of the average values of destructive loads during compression testing of samples

Fig. 13. Comparative analysis of the average values of the tensile strength of samples during compression testing

Conclusion

In the course of the research, mechanical tests of PCM samples with different reinforcement schemes were carried out, that is, a different quantitative ratio of layers of glass wool and roving glass and their binder polyester resin. The test results showed that with an

increase in the number of layers of roving glass in the composition of the PCM, the destructive load and tensile strength, compression increases, but the values of the applied load of PCM samples decrease during three-point bending tests.

References

1. Meieshin M. A., Salamekh Ali, Alsaid Mazen. Opyt primeneniia kompozitsionnykh materialov v sudostroenii [Experience in using composite materials in shipbuilding].

Vestnik Astrakhanskogo gosudarstvennogo tekhnicheskogo

universiteta. Seriia: Morskaia tekhnika i tekhnologiia, 2022, no. 2, pp. 44-50.

2. Pravila klassifikatsii i postroiki morskikh sudov. Part XVI. Konstruktsiia i prochnost' korpusov sudov iz po-limernykh kompozitsionnykh materialov [Rules for the classi-

Вестник Астраханского государственного технического университета.

Серия: Морская техника и технология. 2023. № 3 ISSN 2073-1574 (Print), ISSN 2225-0352 (Online)

Судостроение, судоремонт и эксплуатация флота

fication and construction of sea vessels. Part XVI. Design and strength of ship hulls made of polymer composite materials]. Saint-Petersburg, Izd-vo RMRS, 2019. 151 p.

3. Alsaid Mazen, Salamekh Ali. Sposob izgotovleniia obraztsov iz mnogosloinykh kompozitsionnykh materialov dlia izucheniia ikh mekhanicheskikh svoistv [Method of manufacturing samples from multilayer composite materials for studying their mechanical properties]. Vestnik Astrakhanskogo gosudarstvennogo tekhnicheskogo universiteta. Seriia: Morskaia tekhnika i tekhnologiia, 2018, no. 4, pp. 16-23.

4. Alsaid M., Salamekh A., Mamontov V. A. Issledovanie prochnosti sudostroitel'nogo polimernogo kompozitsionnogo materiala [Studying strength of shipbuilding polymer composite

material]. Vestnik Gosudarstvennogo universiteta morskogo i rechnogo flota imeni admirala S. O. Makarova, 2019, vol. 11, no. 3, pp. 543-553.

5. GOST 4648-2014. Plastmassy. Metod ispytaniia na statisticheskii izgib [GOST 4648-2014. Plastics. Test method for static bending]. Moscow, Standartinform Publ., 2014. 34 p.

6. GOST 11262-2017. Plastmassy. Metod ispytaniia na rastiazhenie [GOST 11262-2017. Plastics. Tensile test method]. Moscow, Standartinform Publ., 2017. 24 p.

7. GOST 4651-2014. Plastmassy. Metod ispytaniia na szhatie [GOST 4651-2014. Plastics. Compression test method]. Moscow, Standartinform Publ., 2014. 19 p.

Список источников

1. Мелешин М. А., Саламех Али, Алсаид Мазен. Опыт применения композиционных материалов в судостроении // Вестн. Астрахан. гос. техн. ун-та. Сер.: Морская техника и технология. 2022. № 2. С. 44-50.

2. Правила классификации и постройки морских судов. Ч. XVI. Конструкция и прочность корпусов судов из полимерных композиционных материалов. СПб.: Изд-во РМРС, 2019. 151 с.

3. Алсаид Мазен, Саламех Али. Способ изготовления образцов из многослойных композиционных материалов для изучения их механических свойств // Вестн. Астрахан. гос. техн. ун-та. Сер.: Морская техника и технология. 2018. № 4. С. 16-23.

4. Алсаид М., Саламех А., Мамонтов В. А. Исследование прочности судостроительного полимерного композиционного материала // Вестн. Гос. ун-та мор. и реч. флота им. адм. С. О. Макарова. 2019. Т. 11. № 3. С. 543-553.

5. ГОСТ 4648-2014. Пластмассы. Метод испытания на статистический изгиб. М.: Стандартинформ, 2014. 34 с.

6. ГОСТ 11262-2017. Пластмассы. Метод испытания на растяжение. М.: Стандартинформ, 2017. 24 с.

7. ГОСТ 4651-2014. Пластмассы. Метод испытания на сжатие. М.: Стандартинформ, 2014. 19 с.

Статья поступила в редакцию 10.05.2023; одобрена после рецензирования 19.07.2023; принята к публикации 15.08.2023 The article was submitted 10.05.2023; approved after reviewing 19.07.2023; accepted for publication 15.08.2023

Information about the authors / Информация об авторах

Maksim A. Meleshin — Postgraduate Student of the Department of Design and Technology of Ship Construction; Volga State University of Water Transport; [email protected]

Максим Алексеевич Мелешин — аспирант кафедры проектирования и технологии постройки судов; Волжский государственный университет водного транспорта; [email protected]

Ali Salamekh — Candidate of Technical Sciences; Professor of the Department of Ship Mechanical Disciplines; Caspian Institute of Sea and River Transport after GeneralAdmiral F. M. Apraksin, branch of Volga State University of Water Transport; [email protected]

Victor A. Mamontov — Doctor of Technical Sciences, Assistant Professor; Professor of the Department of Shipbuilding and Energy Complexes of Marine Engineering; Astrakhan State Technical University; [email protected]

Али Саламех — кандидат технических наук; профессор кафедры судомеханических дисциплин; Каспийский институт морского и речного транспорта имени генерал-адмирала Федора Матвеевича Апраксина, филиал Волжского государственного университета водного транспорта; [email protected]

Виктор Андреевич Мамонтов — доктор технических наук, доцент; профессор кафедры судостроения и энергетических комплексов морской техники; Астраханский государственный технический университет; [email protected]