CC BY
67
Uwe Becker0
ACKNOWLEDGMENT: The authors are indebted to the Deutsche Forschungsgemeinschaft (DFG) and to the Bundesministerium für Bildung und Forschung (BMBF) for the financial support.
CD CO
oo
CP
o
STRONG ENHANCEMENT OF DOUBLE AUGER DECAY FOLLOWING PLASMON EXCITATION IN Ceo 1
<u c o E
tn
Sanja Lj. Koricaa, Axel Reinkosterb,
a University Union - Nikola Tesla, Faculty for Ecology and Environmental Protection, Belgrade, Republic of Serbia + Fritz-Haber-Institut, Department of Molecular Physics Berlin, Federal Republic of Germany, e-mail: [email protected], ORCID iD: < http://orcid.org/0000-0002-7915-9430 b Fritz-Haber-Institut, Department of Molecular Physics, îo
Berlin, Federal Republic of Germany &
c Fritz-Haber-Institut, Department of Molecular Physics, ^
Berlin, Federal Republic of Germany &
DOI: 10.5937/vojtehg66-16269; https://doi.org/10.5937/vojtehg66-16269 <
el
FIELD: molecular physics, synchrotron radiation, photoelectron spectroscopy, -a fullerenes, dipole resonance, Auger decay, Plasmon, collective o
oscillation, localized excitation, delocalized relaxation ARTICLE TYPE: Original Scientific Paper ARTICLE LANGUAGE: English
Abstract:
One of the important characteristics of the C60 molecule is the collective response of its valence electron cloud to the electromagnetic radiation. This collective behavior gives rise to the occurrence of the giant dipole resonance (so called surface plasmon) in the absorption spectrum centered around 20 eV, which has also been analyzed theoretically by various authors. Concerning photoelectron emission, plasmonic excitation is characterized by a particular intensity behavior near the threshold. We present here a new series of the K-shell photoelectron spectra with particular emphasis on the qualitative analysis of all ionization with excitation and double ionization processes. Our 5 measurements of the C60 plasmon excitation follow the so-called Thomas-Derrah law and are in good agreement with the corresponding behavior of satellite excitations in atoms such as neon. Key words: molecular physics, photoelectron spectroscopy, plasmon excitation.
<u E <u o
<u
O) c o
OT
m •*—•
(D
OT
(0 O
CO <D
CD CD
"5 >
03
o CM
of
UJ
a.
Z) O
o <
o
X
o
LU
H >-
OH <
H
<
CD >o
X UJ
H O
O >
Introduction
Since the discovery of C60 molecule (Kroto et al, 1985, pp.162-163), (Kratschmer et al, 1990, pp.354-358) many studies have been performed to investigate its fundamental properties. These properties are mainly driven by its unique molecular structure like a spherical shell (Electronic Properties of Fullerenes, 1993), (Korica et al, 2005, pp.132031-132035). C60 is known to have a plasmon excitation where 240 valence electrons contribute to a delocalized electron cloud that can oscillate relative to the carbon ion core forming the C60 molecular cage. This oscillation produces a giant resonance in the C60 photoabsorption (Hertel et al, 1992, pp.784787) and electron-energy-loss spectra (Leiro et al, 2003, pp.205-213) at the excitation energy of about 20eV. It has also been observed in the photofragmentation experiments as an enhanced relative fragmentation of C60+ ion at the same photon energy (Karvonen et al, 1997, pp.34663472). It has been interpreted by different theoretical models as a dipole collective giant resonance (Amusia & Connerade, 2000, pp.41-70), (Bertsch et al, 1991, pp.2690-2693), (Ekardt, 1984, pp.1925-1928), due to autoionization, which arises from collecting the strength of the individual one-electron transitions into a single collective excitation.
Experimental set-up
The measurements were performed at the HASYLAB undulator beam line BW3 in Hamburg using monochromatized synchrotron radiation whose wavelength can be scanned with a resolution set to an appropriate value. The photon beam crosses an effusive beam of C60 molecules, provided by an oven heated to 500 °C. Outgoing electrons are detected in time-of-flight (TOF) electron spectrometers at two different angles with respect to the electric vector of the ionizing radiation (Fig. 1). Appropriate voltages can be applied to the TOF-analysers to keep a constant resolution of the electron spectra for different photon energies.
storage ring
synchrotron radiation
molecular beam source
Figure 1 - The experimental set-up Рис. 1 - Экспериментальная аппаратура Слика 1 - Експериментална апаратура
Results and Discussion Plasmon excitation in C60 molecule
Figure 2 shows an example of the K-shell photoelectron spectrum of C60, recorded at 390 eV photon energy, covering the whole range of kinetic energies down to zero kinetic energy. The spectrum is converted to the binding energy and the background has been subtracted.
The spectrum consists, besides the single narrow C(1s) main line (Lichtenberger et al, 1991, pp.203-208), of a variety of satellite lines and higher lying plasmon excitation (Weaver et al, 1991, pp.1741-1744), (Benning et al, 1992, pp.6899-6913), (Terminello et al, 1991, pp.491496). The low binding energy side of the C1s (from 1.9 eV to 9.3 eV) is characterized by different dipole and monopole shake-up satellites, except the one at the 6.0 eV which relates to the n plasmon. The energy region between 10 eV and 20 eV does not have discrete dipole transitions for free molecules and collective resonances are the dominating effects here (plasmon like excitations). The broad peak at the high binding energy side is also caused by several plasmon excitations.
Such plasmons are supposed to originate from a collective motion of a- and/or п-electrons in the electric hull of the C60 molecules following the ionization of a K-shell electron.
CO CO
oo
CP
О
о +-<
го
-w
о X ф с о Е
(Л
го
^
го
о ф
тз ф
сл <
_Q
о тз
ф
Е ф
о
ф
О) с о
ю
"rô ф
ся
(О с^
сз
со ф
CD CD
"о
>
О
см
ОС LLJ
ОС ZD О
О _|
< с;
X О ш
н
>-
ОС <
(Л <
-J
О >о
X ш н
о
о >
Figure 2 - A recorded spectrum of the 54.7°- analyser for a photon energy of 390eV Рис. 2 - Анализатор спектра на 54.7°для энергии фотона 390eV Слика 2 - Спектар анализатора на 54,7° за енергиу фотона од 390 eV
We have also studied the dynamical behaviour of plasmon excitation by recording the photoelectron spectra as a photon energy function. This is illustrated in Figure 3 for several different photon energies.
Figure 3 - Spectra as a function of the binding energy of the 180°-analyser for different
photon energies
Рис. 3 - Спектр в функции связной энергии анализатора на 180° для различных
уровней энергии фотона Слика 3 - Спектар у функциjи од енерги'е везе за анализатор на 180° за различите енерги'е фотона
1 f 0
r A
l \ _
AE[eV]| /(15.32Eex[eV]L, (1)
CD
co 00
Our results are in good agreement with the model of T. D. Thomas (Thomas, 1984, pp.417-420), a time-dependent model which describes the transition between adiabatic and sudden behaviour. It takes into account the interaction between the outgoing electron and the remaining electrons which leads to shake-up satellite electrons because the photoejected electron may emerge with less energy than in the adiabatic picture. In addition, multiple electron ejection is possible, in which case a 3 continuous shake-off spectrum is observed since the discrete energy can be arbitrarily divided between the emitted electrons. In the frame of this model, the intensity ratio of the "shake-up" process and the C(1s) line is § given by the expression:
o
o
5 o
ro o <u
T3
where:
¡i - intensity ratio of the "shake-up" process and the C(1s) main line, <
¡um - asymptotic value of ^ (taken from Leiro et al, 2003, pp.205-213), 25
r - the distance until the electrons are separated from the molecule, -§
r ~ 0.4A, note: r << r(C60),
AE - the excitation energy of the "shake-up" process, Eex - the kinetic energy of the outgoing electrons.
Figure 4 shows a comparison of the experimental results with the results of the model of T. D. Thomas (Thomas, 1984, pp.417-420). With increasing energy, the plasmon intensity reaches its sudden limit faster than expected pointing to the localized excitation processes rather than to a delocalized relaxation in response to core-hole creation. The sudden limit intensity is as large as 30% of the total K-shell ionization events. Our o> measurements are in good agreement with the corresponding behavior of the satellite excitations in atoms such as He, Ne and Ar (Holland et al, o 1979, pp.2465-2484) where electron correlation effects are supposed to enhance various cross sections.
<u
O) c o
OT
"ro
<u
2
со ф
CD CD
"о
>
О
см
ОС LLJ
ОС
о
о _|
< с;
X О ш
н
>-
ОС <
да1 и
с
о
О.
80
60
40
20
4h
чг
300 400 500
Photon energy (eV)
-1—/Н— 600 "1000
1500
(Л <
-J
О >о
X ш н
о
о >
Figure 4 - Experimental and calculated values of the ratio of the intensity of all plasmon
peaks and the intensity of the C(1s) main line as a function of excitation energy. Рис. 4 - Экспериментальные и расчетные значения отношений интенсивности всех плазмонных пиков и интенсивности C(1s) главной линии в функции энергии
возбуждения.
Слика 4 - Експериментална и израчуната вредност односа интензитета свих пикова плазмона и интензитета C(1s) главне лини]е у функции енерги^е
ексцитаци^е
Double Auger decay of the excited C60
The strength of the shake-off processes contributes also significantly to total K-shell ionization rate. The relative fraction of this shake-off rate has been, however, unknown so far, although the complete photoelectron spectra exhibit a large fraction of continuously distributed photoelectron intensity which could either result from shake-off photoelectron emission or double Auger decay (Fig.5). The quality of the former K-shell photoelectron measurements was insufficient to disentangle these two contributions experimentally (Aksela et al, 1995, pp.2112-2115), (LeBrun et al, 1994, pp.3965-3968), (Bruhwiler et al, 1993, pp.3721-3724), (Krummacher et al, 1993, pp.8424-8429).
The contribution of different excitation events can by separated with the ansatz (Fig.5):
Total Auger = Augersmgle+ Augerdouble
= C(1s) + Satellites + Plasmons + eshakeoff
0
■■¡г
СП
■■¡г со оо ■■¡г
О
о +-<
го
(J
X ф
с о Е
(Л
го
^
го
о ф
тз ф
сл <
_Q
о тз
Figure 5 - Photoelectron spectrum recorded with a photon energy of 390eV. Different types of contributions are marked with colours. The intensity of the single and double Auger process can be deduced from the coloured areas.
Рис. 5 - Фотоэлектронный спектр, записанный для энергии фотона 390eV. Различные виды влияния обозначены разными цветами. Интенсивность Оже-процессов можно определить по обозначенным частям.
Слика 5- Фотоелектронски спектар снимл^ен за енергиу фотона 390eV.
Различите врсте доприноса означене су различитим боjама. Интензитети Ожеових процеса могу се одредити из обоjених области.
Performing a spectral analysis, which takes all primary and secondary ionization events into account, yields a double Auger rate as high as 60% of the total Auger yield. This is an extremely high value, raising the question of its origin. Assuming that the main line and the related shake-off emission result predominantly in single Auger decay, the K-shell photoionization associated with satellite and plasmon excitations remain the only plausible source for such a high double Auger rate.
The only reason for this highly unusual behaviour may be the fact that satellite and plasmon excitations both populate LUMO states which
ф E ф о
Ф О) с
о +-<
Ю
"го ф
ся
го" о
о
CO <D
CD CD
"o >
03
o CM
of
UJ
a.
Z) O
o <
o
X
o
LU
H ^
a. <
H
<
CD >o
X LU H O
O >
are strongly delocalized and may be completely in the continuum for the double charged C60 ion resulting from the K-shell ionization and the subsequent core-hole refilling process (Maxwell et al, 1994, pp.1071710725), (Wastberg et al, 1994, pp.13031-13034). The excited electron cannot survive in this unstable situation and will consequently leave the C60 ion along with the Auger electron in a form of an Auger shake-off transition. These arguments, however, have to be validated by more sophisticated calculations.
Conclusion
We have studied the C60 molecule photoionization above the C(1s) threshold, in the photon energy range hv=(330-390)eV. A careful analysis of the spectra yielded two surprising and unexpected results:
(i) With energy increase, the plasmon intensity reaches its sudden limit faster than expected pointing to localized excitation processes rather than to a delocalized relaxation in response to core-hole creation. The sudden limit intensity is as large as 30% of the total K-shell ionization events.
(ii) Performing a spectral analysis taking all primary and secondary ionization events into account yields a double Auger rate as high as 60% of the total Auger yield.
The double Auger processes are probably linked to the plasmon excitation in the C60 molecules.
References
Aksela, S., Nommiste, E., Jauhiainen, J., Kukk, E., Karvonen, J., Berry, H.G., Sorensen S.L., Aksela, H. 1995. Photofragmentation of C60 Molecules following Resonance Excitation and ionization near the C1s Edge. Physical Review Letters, 75(11), pp.2112-2115. Available at: h1tps://doi.org/10.1103/physrevlett.75.2112.
Amusia, M.Ya., & Connerade, J.P. 2000. The theory of collective motion probed by light. Reports on Progress in Physics, 63(1), pp.41-70. Available at: https://doi.org/10.1088/0034-4885/63/1/202.
Benning, P.J., Poirier, D.M., Ohno, T.R., Chen, Y., Jost, M.B., Stepniak, F., Kroll, G.H., Weaver, J.H., Fure, J., & Smalley, R.E. 1992. C60 and C70 fullerenes and potassium fullerides. Physical Review B, 45(12), pp.6899-6913. Available at: https://doi.org/10.1103/physrevb.45.6899.
https://doi.org/10.1038/318162a0.
Krummacher, S., Biermann, M., Neeb, M., Liebsch, A., & Eberhardt, W. 1993. Close similarity of the electronic structure and electron correlation in gasphase and solid C60. Physical Review B, 48(11), pp.8424-8429. Available at: https://doi.org/10.1103/physrevb.48.8424.
CD
Bertsch, G.F., Bulgac, A., Tomanek, D., & Wang, Y. 1991. Collective ^T Plasmon excitations in C60 clusters. Physical Review Letters, 67(19), pp.26902693. Available at: https://doi.org/10.1103/physrevlett.67.2690.
Brühwiler, P.A., Maxwell, A.J., Rudolf, P., Gutleben, C.D., Wästberg, B., & Martensson, N. 1993. C1s autoionization study of electron hopping rates in solid o C60. Physical Review Letters, 71(22), pp.3721-3724. Available at: https://doi.org/10.1103/physrevlett.71.3721. °
Ekardt, W. 1984. Dynamical Polarizability of Small Metal Particles: Self- ~ Consistent Spherical Jellium Background Model. Physical Review Letters, § 52(21), pp.1925-1928. Available at: https://doi.org/10.1103/physrevlett.52.1925. 0
Electronic Properties of Fullerenes. Proceedings of the International E Winterschool on Electronic Properties of Novel Materials. [e-book]. Edited by ^ Kuzmany, H., Fink, J., Mehring, M., Roth, S. Tirol, March 6-13, 1993. Berlin: Springer Series in Solid-State Sciences, Vol.177. Available at: http://www.springer.com/gp/book/9783642850516. Accessed: 28 October 2017.
Hertel, I.V., Steger, H., de Vries, J., Weisser, B., Menzel, C., Kamke, B., & ^ Kamke, W. 1992. Giant plasmon excitation in free C60 and C70 molecules studied 2 by photoionization. Physical Review Letters, 68(6), pp.784-787. Available at: https://doi.org/10.1103/physrevlett.68.784.
Holland, D.M.P., Codling, K., Marr, G.V., & West, J.B. 1979. Multiple =3 photoionisation in the rare gases from threshold to 280 eV. Journal of Physics B: Atomic and Molecular Physics, 12(15), pp.2465-2484. Available at: https://doi.org/10.1088/0022-3700/12Z15/008.
Karvonen, J., Nömmiste, E., Aksela, H., & Aksela, S. 1997. Photoion spectra of C60 molecules at resonance excitation and ionization energies near the C1s edge. The Journal of Chemical Physics, 106(9), pp.3466-3472. | Available at: https://doi.org/10.1063/1.473442. °
Korica, S., Rolles, D., Reinköster, A., Langer, B., Viefhaus, J., Cvejanovic, S., & Becker, U. 2005. Partial cross sections and angular distributions of ® resonant and non-resonant valence photoemission of C60. Physical Review A, g 71(1), pp.132031-132035. Available at: https://doi.org/10.1103/physreva.71.013203. $
Krätschmer, W., Lamb, L.D., Fostiropoulos, K., & Huffman, D.R. 1990. Solid C60: a new form of carbon. Nature, 347(6291), pp.354-358. Available at: -53 https://doi.org/10.1038/347354a0. ot
Kroto, H.W., Heath, J.R., O'Brien, S.C., Curl, R.F., & Smalley, R.E. 1985. g C60: Buckminsterfullerene. Nature, 318(6042), pp.162-163. Available at: '§
CO
LeBrun, T., Berry, H.G., Cheng, S., Dunford, R.W., Esbensen, H., Gemmell, D.S., Kanter, E.P., & Bauer, W. 1994. Ionization and Multifragmentation of C60 by High-Energy, Highly Charged Xe Ions. Physical Review Letters, 72(25), pp.3965-3968. Available at: https://doi.org/10.1103/physrevlett.72.3965. > Leiro, J.A., Heinonen, M.H., Laiho, T., & Batirev, I.G. 2003. Core-level XPS
spectra of fullerene, highly oriented pyrolitic graphite, and glassy carbon. Journal
о
° of Electron Spectroscopy and Related Phenomena, 128(2-3), pp.205-213. a: Available at: https://doi.org/10.1016/s0368-2048(02)00284-0.
Lichtenberger, D.L., Nebesny, K.W., Ray, C.D., Huffman, D.R., & Lamb, g L.D. 1991. Valence and core photoelectron spectroscopy of C60,
0 buckminsterfullerene. Chemical Physics Letters, 176(2), pp.203-208. Available ^ at: https://doi.org/10.1016/0009-2614(91)90155-3. ^ Maxwell, A.J., Brühwiler, P.A., Nilsson, A., Märtensson, N., & Rudolf, P.
1 1994. Photoemission, autoionization, and x-ray-absorption spectroscopy of ft ultrathin-film C60 on Au(110). Physical Review B, 49(15), pp.10717-10725. ^ Available at: https://doi.org/10.1103/physrevb.49.10717. cic Terminello, L.J., Shuh, D.K., Himpsel, F.J., Lapiano-Smith, D.A., Stöhr, J., ^ Bethune, D.S., & Meijer, G. 1991. Unfilled orbitals of C60 and C70 from carbon K-
shell X-ray absorption fine structure. Chemical Physics Letters, 182(5), pp.491496. Available at: https://doi.org/10.1016/0009-2614(91)90113-n.
Thomas, T.D. 1984. Transition from Adiabatic to Sudden Excitation of Core w Electrons. Physical Review Letters, 52(6), pp.417-420. Available at:
https://doi.org/10.1103/physrevlett.52.417. - Wästberg, B., Lunell, S., Enkvist, C., Brühwiler, P.A., Maxwell, A.J., &
o Märtensson, N. 1994. 1s x-ray-absorption spectroscopy of C60: The effects of
x
screening and core-hole relaxation. Physical Review B, 50(17), pp.13031-13034. uj Available at: https://doi.org/10.1103/physrevb.50.13031. o Weaver, J.H., Martins, J.L., Komeda, T., Chen, Y., Ohno, T.R., Kroll, G.H.,
Troullier, N., Haufler, R.E., & Smalley, R.E. 1991. Electronic structure of solid > C60: Experiment and theory. Physical Review Letters, 66(13), pp.1741-1744. Available at: https://doi.org/10.1103/physrevlett.66.1741.
УСИЛЕНИЕ ДВОЙНОГО ОЖЕ-РАСПАДА, СОПРОВОЖДАЮЩЕГО ВОЗБУЖДЕНИЕ ПЛАЗМОНОВ В Сао
Саня Л. Корицаа, Аксел Райнкостер6, Уве Бекер"
Университет «Унион - Никола Тесла», Факультет экологии и охраны окружающей среды, г. Белград, Республика Сербия + Институт им. Фрица Габера, Отделение молекулярной физики, г. Берлин, Федеративная Республика Германия 1 Институт им. Фрица Габера, Отделение молекулярной физики, г. Берлин, Федеративная Республика Германия Институт им. Фрица Габера, Отделение молекулярной физики, г. Берлин, Федеративная Республика Германия
ОБЛАСТЬ: молекулярная физика, синхротронное излучение, ^
Фотоэлектронная спектроскопия, фуллерены, дипольный резонанс, Оже-распад, плазмон, S3
CP
коллективные колебания, локализованное возбуждение, делокализованная релаксация ВИД СТАТЬИ: оригинальная научная статья ЯЗЫК СТАТЬИ: английский
Саъа Корицаа, Аксел Ра]нкостерб, Уве Бекерв
о
го
Резюме: о
Одной из самых значительных свойств молекулы С6о является ^ коллективная реакция ее валентных электронов на 8 электромагнитные излучения. Вследствие коллективной реакции § в спектре поглащения возникает огромный дипольный резонанс | (так называемый поверхностный плазмон), приблизительно на 20 eV, который был неоднократно представлен различными авторами в их теоретических исследованиях. В случае фотоэлектронной эмиссии, наблюдаются характерное поведение плазмонов при возбуждении на пороге ионизации. В работе ^ представлена новая серия фотоэлектронных спектров К- S оболочки, а также подробный квалитативный анализ всех 73 ионизаций с возбуждениями в процессе двойной ионизации. На основании проведенного анализа и измерений плазмонного возбуждения С60 при применении так называемого закона Томас-Дерраха можно утверждать, что они полностью совпадают с соответствующим поведением сателлитного возбуждения атомов в неонах.
Ключевые слова: молекулярная физика, фотоэлектронная е спектроскопия, возбуждение плазмонов. о
JAKO nOJA4AtoE ДВОСТРУКОГ ОЖЕОВОГ РАСПАДА КОиИ ПРАТИ ПЛАЗМОНСКУ ЕКСЦИТАЦШУ У Сао
о
ф
(Л
Универзитет Унион - Никола Тесла, Факултет за екологи]у и заштиту животне средине, Београд, Република Срби]а + Институт Фриц Хабер, Одсек за молекуларну физику, Берлин, Савезна Република Немачка б Институт Фриц Хабер, Одсек за молекуларну физику,
Берлин, Савезна Република Немачка ^
в Институт Фриц Хабер, Одсек за молекуларну физику, Берлин, Савезна Република Немачка
ОБЛАСТ: физика молекула, синхротронско зраче^е, фотоелектронска спектроскопи]а, фулерени, диполна резонанца, Ожеов распад, Плазмон, колективна осцилаци]а, локализована ексцитаци]а, делокализована релаксаци]а ВРСТА ЧЛАНКА: оригинални научни чланак JЕЗИК ЧЛАНКА: енглески
СО
0
01
« Сажетак:
<D
JedHa од знача]них карактеристика С60 молекула je колективни одговор кегових валентних електрона на електромагнетно «э зрачеке. Ово колективно понашаке доводи до по}аве огромне
о диполне резонанце (тзв. површински плазмон) у апсорпционом
спектру на око 20 eV, ко]и су различити аутори и теори]ски анализирали. Када }е у питаку фотоелектронска емисща, плазмонску ексцитаци]у карактерише посебно понашаке на прагу Si ]онизаци]е. Приказана jе нова сери]а фотоелектронских спектара
S К-л>уске са тежиштем на квалитативноj анализи свих ]онизаци]а
о са ексцитаци]ама и процесима двоструке ]онизаци]е. Мерека
° плазмонске ексцитаци]е С60 прате тзв. Томас-Дирахов закон и у
< велико] су сагласности са одговара}уЬим понашакем сателитских
ексцитаци]а у атомима као што jе неон.
о Къучне речи: физика молекула, фотоелектронска
спектроскоп^а, плазмонска ексцитацща.
>
^ Paper received on / Дата получения работы / Датум приема чланка: 15.01.2018.
Manuscript corrections submitted on / Дата получения исправленной версии работы / Датум достав^а^а исправки рукописа: 07.04.2018.
Paper accepted for publishing on / Дата окончательного согласования работы / Датум коначног прихвата^а чланка за об]ав^ива^е: 09.04.2018.
^ © 2018 The Authors. Published by Vojnotehnicki glasnik / Military Technical Courier
(www.vtg.mod.gov.rs, втг.мо.упр.срб). This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/rs/).
>Q
© 2018 Авторы. Опубликовано в «Военно-технический вестник / Vojnotehnicki glasnik / Military i_u Technical Courier» (www.vtg.mod.gov.rs, втг.мо.упр.срб). Данная статья в открытом доступе и
О
распространяется в соответствии с лицензией «Creative Commons» (http://creativecommons.Org/licenses/by/3.0/rs/).
О © 2018 Аутори. Обjавио Воjнотехнички гласник / Vojnotehnicki glasnik / Military Technical Courier (www.vtg.mod.gov.rs, втг.мо.упр.срб). Ово je чланак отвореног приступа и дистрибуира се у складу са Creative Commons licencom (http://creativecommons.org/licenses/by/3.0/rs/).
