Научная статья на тему '金属表面化学镀 NI-B 镀层的原理和应用'

金属表面化学镀 NI-B 镀层的原理和应用 Текст научной статьи по специальности «Физика»

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化学镀 Ni-B / 原理 / 应用 / electroless Ni-B / principle / application

Аннотация научной статьи по физике, автор научной работы — Hu Zekui, Mei Shunqi, Alexey Guryev, Burial Lygdenov

Ni-B 镀层由于其厚度均匀, 高硬度, 抗磨损, 耐腐蚀, 自润滑等优良的特性, 广泛应用于纺织, 航空航天, 汽车, 轮船等领域. 本文主要介绍了化学镀 Ni-B 镀层的原理和应用, 最后展望了化学镀镍硼镀层的发展趋势, 认为化学镀未来可朝着适配性强, 兼容性高的优良化学镀 Ni-B 镀液, 镀法的方向发展, 实现一种溶液或金属表面处理方法适用于多种金属.

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Principle and metal surface application of electroless Ni-B plating

Ni-B plating is widely used in textile, aerospace, automotive, ship and other fields due to its excellent characteristics such as uniform thickness, high hardness, anti-wear, corrosion resistance and self-lubrication. In this paper mainly introduces the principle and application of electroless Ni-B plating, and finally looks forward to the development trend of electroless Ni-B plating. It is believed that the future of electroless plating can be developed towards the direction of excellent electroless Ni-B plating solution and plating method with strong adaptability and high compatibility, so that a solution or metal surface treatment method can be applied to a variety of metals.

Текст научной работы на тему «金属表面化学镀 NI-B 镀层的原理和应用»

For citation: Hu Zekui, Mei Shunqi, Alexey Guryev, Burial Lygdenov. Principle and metal

surface application of electroless Ni-B plating // Grand Altai Research & Education —

Issue 1 (19)'2023 (DOI: 10.25712/ASTU.2410-485X.2023.01) — EDN: https://elibrary.ru/jhxnto

UDK 544.654.2

Principle and metal surface application

of electroless Nl-B plating

Hu Zekui1, Mei Shunqi1, Alexey Guryev1'2, Burial Lygdenov1'3

1 Hubei Digital Textile Equipment Key Laboratory, Wuhan Textile University, Wuhan, China 2 Zhejiang Taitan Co., Ltd, Zhejiang Xinchang, China 3 Zhejiang Xinchang Sanxiong Bearing Co., Ltd, Zhejiang Xinchang, China E-mail: 863076403@qq.com ; meishunqi@vip.sina.com

Abstract. Ni-B plating is widely used in textile, aerospace, automotive, ship and other fields due to its excellent characteristics such as uniform thickness, high hardness, anti-wear, corrosion resistance and self-lubrication. In this paper mainly introduces the principle and application of electroless Ni-B plating, and finally looks forward to the development trend of electroless Ni-B plating. It is believed that the future of electroless plating can be developed towards the direction of excellent electroless NiB plating solution and plating method with strong adaptability and high compatibility, so that a solution or metal surface treatment method can be applied to a variety of metals.

Keywords: electroless Ni-B; principle; application

шш^ш ni-B ттшттт

mm1, rnjm1, ^шт^шшш^1'2, шштт^шш*1'3

E-mail: 863076403@qq.com ; meishunqi@vip.sina.com

rnМ: Ni-в йШ, rnrnrn, МШЙ,

Пт№ШЯ, да, &ШШШ. Ni-B Ш

мшдапш, й^мшт^шшяшмй^мт

^ШШМ, МШМШШШNi-B шш, шшшш, ш-шш

^Ш Ni-B; ШЖ; Ш

0 ЩЙ

жтш^-, ^шш&айЛйш^ш (en), чшш (cvd), шшш (lc) щ [1]. кш Ni-в шт

тш, Шй, ЙШ, Ш^Щ^ЁЙШ^, тшхтш, тш, ш, тщ, тшш, т$тя, п^, шщмшттг%м№ [2].

яхяшт^ш Ni-в штштшшшш, x^mitxt Ni-в ш тшшшттшшштж, ттшшшш Ni-в шт^ш ш&шшшттш.

1 ШШ Ni-в ШШ&МШ

1946 Brenner m Riddle МЙЛ, М^Т^Ш^ШШШ^ (Electroless Plating) [3]. 1954 ^

m ^шшшшштшш®, мяш, дещшш^ш тштшпм. 1968 тшшшшшштш, &шшштш

тт 20 ш 70 m иттвшшш^т^х^г, x ттш&ъ-штшш&тш. ЙЛВШШ-^ЙШ, ушйш

тшштттшня 20 ш 80

Ш, тшжштшшшшш [4]. 21 шшшшш ш&тйш [5]. тш, »п#ш»мощ,

2 ^ш Ni-в штшж 2.1

жшп^я, тшшт, т^, ^ттшшишшшм, ^w, м2+, й^шшт

тттш&шштшт, Ш2 ш.

4Ni2++BH4-+8OH--►B(OH)4-+4Ni+4H2O (2-1)

Ж-^тЭДМШШЙ^ 1:1, Й^ШШШ^:

2Ni2++4H2O+2BH4--► 2Ni+B+B(OH)4-+3H++^H2 (2-2)

mi

1) SM; 2) Ä 3) 4) iPÄg; 5) »^S Figure 1. Electroless plating device 1) Lanyard; 2) Plating solution; 3) Substrate; 4) Heating device; 5) Mixing device

Figure 2. Principle of electroless plating

2.2

шм, mm ph ^^

M [5], ЯЯж,

шж^тшш, тшш,

шшщ.

^^М: ттмшш, мш&ш, ^шшт^

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адш^мшш^ш. № шшнэд,

PH iM^MO: гМ^ШШ pH,

т {ьтштяшж^мтт

Table 1. Main composition of electroless nickel-boron plating solution

(g/L)

ТЖ-ПИ 20-30 Ошибка! Источник ссылки не найден. -Ошибка! Источник ссылки не найден.

6 Ошибка! Источник ссылки не найден.

йШ адшш 0.4-1.2 Ошибка! Источник ссылки не найден.

адш^ 0.5-2 Ошибка! Источник ссылки не найден.

1 Ошибка! Источник ссылки не найден.

60-120 Ошибка! Источник ссылки не найден.

7 Ошибка! Источник ссылки не найден.

20-40 Ошибка! Источник ссылки не найден.

шш 0.11 Ошибка! Источник ссылки не найден.

0.02 Ошибка! Источник ссылки не найден.Ошибка! Источник ссылки не найден.Ошибка! Источник ссылки не найден.

0.015 Ошибка! Источник ссылки не найден.

mm 1 Ошибка! Источник ссышки не найден. -Ошибка! Источник ссышки не найден.

nwrn^ 20-40

pH il^O ^шШ рн, ттшжж^шж 40 Ошибка! Источник ссылки не найден.

РЖ Ошибка! Источник ссылки не найден.

3 Ni-B

3.1 Ni-B

Х^ФШй^Ж, ШШ Ni-B ШЖШШЙ^Г^. [16]

Ni-в шшмттш

МШ\. F. Buibui [17] йЗД^Ф, ^ШШШШМШЯ^ aisi 304

штп L9

wan y [is] тш

ЖМ PTFE Ш^ШШЙ aisi 52100 Ni-B

3.2 ШШ&ШШ Ni-B

M. Vijayanand [19]

(Ш, ШМ 7075-T6

r. Petro [20] т№$7-шмт'\тттш&жш

AZ91D т AM50

V. Vitry [21] Al-Cu-Mg

(95%Ar+5%H2) ЧШТШШ&Ш,

E. Correa [15] ШШ&ШМКШШШШШ, Ni-B Ш

тштшшшм.

3.3 Ш&ШШ Ni-B

S. Ziyuan [7]

[22] тжшшшшя

±Ш7ШШ, М«п#±, Ni-B М

% [13] жшШ^ХЙЙШЖ (^жтттшт)

fAmMttm.

Ni-B , mm, ^^

m m m, ^M, ^»it^m

im

Mft^nM*!^. 4

Ni-B 0

ft, sm^ffffMMMRTOMiffJ

Itt^^ff Ni-B «, ff^I^m

[1] m MtA [J]. l^m 2022, 49(06):35-39.

[2] Unal E., Ya§ar A., Karahan i.H. A review of electrodeposited composite coatings with Ni-B alloy matrix [J]. Materials Research Express, 2019, 6(9): 092004.

[3] Brenner A. Nickel plating on steel by chemical reduction [J]. J. Research Natl. Bur. Standards, 1946, 37: 31.

[4] MS, «a [J]. tfflWfe^Mm 2019, 29(09):2192-2216.

[5] Vitry V., Hastir J., Megret A., et al. Recent advances in electroless nickel-boron coatings [J]. Surface and Coatings Technology, 2022, 429: 127937.

[6] Srinivasan K.N., Meenakshi R., Santhi A., et al. Studies on development of electroless Ni-B bath for corrosion resistance and wear resistance applications [J]. Surface Engineering, 2010, 26(3): 153-158.

[7] Ziyuan S., Deqing W., Zhimin D. Surface strengthening pure copper by Ni-B coating [J]. Applied Surface Science, 2004, 221(1-4): 62-68.

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[8] Hamid Z.A., Hassan H.B., Attyia A.M. Influence of deposition temperature and heat treatment on the performance of electroless Ni-B films [J]. Surface and coatings technology, 2010, 205(7): 2348-2354.

[9] Bonin L., Castro C.C., Vitry V., et al. Optimization of electroless NiB deposition without stabilizer, based on surface roughness and plating rate [J]. Journal of Alloys and Compounds, 2018, 767: 276-284.

[10] Vijayanand M., Varahamoorthi R., Kumaradhas P., et al. Process Modeling and Intuitive Search Based Optimization of Average Surface Roughness in Citrate Stabilized Electroless Nickel-Boron Coatings [J]. JOM, 2022, 74(2): 563-573.

[11] Delaunois F., Lienard P. Heat treatments for electroless nickel-boron plating on aluminium alloys [J]. Surface and Coatings Technology, 2002, 160(2-3): 239-248.

[12] Vitry V., Delaunois F., Dumortier C. Mechanical properties and scratch test resistance of nickel-boron coated aluminium alloy after heat treatments [J]. Surface and Coatings Technology, 2008, 202(14): 3316-3324.

[13] m^. Ni-B [D]. mmmx^, 2021. 2021.000822.

[14] Arias S., Castaño J.G., Correa E., et al. Effect of heat treatment on tribological properties of Ni-B coatings on low carbon steel: wear maps and wear mechanisms [J]. Journal of Tribology, 2019, 141(9): 091601.

[15] Correa E., Mejía J.F., Castaño J.G., et al. Tribological characterization of electroless Ni-B coatings formed on commercial purity Magnesium [J]. Journal of Tribology, 2017, 139(5).

[16] MM, mv#. mmmMm^wmrnt^m. NÍ-B J

^U, 2020, 40(02):22-24.

[17] Bulbul F. The effects of deposition parameters on surface morphology and crystallographic orientation of electroless Ni-B coatings [J]. Metals and Materials International, 2011, 17: 67-75.

[18] Wan Y., Yu Y., Cao L., et al. Corrosion and tribological performance of PTFE-coated electroless nickel boron coatings [J]. Surface and Coatings Technology, 2016, 307: 316-323.

[19] Vijayanand M., Varahamoorthi R., Kumaradhas P., et al. Modelling and optimisation of hardness in citrate stabilised electroless nickel boron (ENi-B) coatings using back propagation neural network-Box Behnken design and simulated annealing-genetic algorithm [J]. Transactions of the IMF, 2021, 99(5): 253-264.

[20] Petro R., Schlesinger M. Direct electroless deposition of nickel boron alloys and copper on aluminum containing magnesium alloys[J]. Electrochemical and Solid-State Letters, 2011, 14(4): D37.

[21] Vitry V., Delaunois F., Dumortier C. Mechanical properties and scratch test resistance of nickel-boron coated aluminium alloy after heat treatments[J]. Surface and Coatings Technology, 2008, 202(14): 3316-3324.

[22] mm, nrnrn^. rn± Eu xm^m NÍ-B ^rnmm m. 2020,

53(05):92-95. References

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[3] Brenner A. Nickel plating on steel by chemical reduction [J]. J. Research Natl. Bur. Standards,1946,37: 31.

[4] Qin Zhenbo, Wu Zhong, Hu Wenbin. Application of surface engineering technology and its research status [J]. Chinese Journal of Nonferrous Metals, 2019, 29(09):2192-2216.

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[6] Srinivasan K.N., Meenakshi R., Santhi A., et al. Studies on development of electroless Ni-B bath for corrosion resistance and wear resistance applications [J]. Surface Engineering, 2010, 26(3): 153-158.

[7] Ziyuan S., Deqing W., Zhimin D. Surface strengthening pure copper by Ni-B coating [J]. Applied Surface Science, 2004, 221(1-4): 62-68.

[8] Hamid Z.A., Hassan H.B., Attyia A.M. Influence of deposition temperature and heat treatment on the performance of electroless Ni-B films [J]. Surface and coatings technology, 2010, 205(7): 2348-2354.

[9] Bonin L., Castro C.C., Vitry V., et al. Optimization of electroless NiB deposition without stabilizer, based on surface roughness and plating rate [J]. Journal of Alloys and Compounds,

2018, 767: 276-284.

[10] Vijayanand M., Varahamoorthi R., Kumaradhas P., et al. Process Modeling and Intuitive Search Based Optimization of Average Surface Roughness in Citrate Stabilized Electroless Nickel-Boron Coatings [J]. JOM, 2022, 74(2): 563-573.

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[12] Vitry V., Delaunois F., Dumortier C. Mechanical properties and scratch test resistance of nickel-boron coated aluminium alloy after heat treatments [J]. Surface and Coatings Technology, 2008, 202(14): 3316-3324.

[13] Jia Yao. Preparation of chemically plated Ni-B coatings on titanium alloys and study of their tribological behavior [D]. Southwest University of Science and Technology,2021. 2021.000822.

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2019, 141(9): 091601.

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[19] Vijayanand M., Varahamoorthi R., Kumaradhas P., et al. Modelling and optimisation of hardness in citrate stabilised electroless nickel boron (ENi-B) coatings using back propagation neural network-Box Behnken design and simulated annealing-genetic algorithm [J]. Transactions of the IMF, 2021, 99(5): 253-264.

[20] Petro R., Schlesinger M. Direct electroless deposition of nickel boron alloys and copper on aluminum containing magnesium alloys[J]. Electrochemical and Solid-State Letters, 2011, 14(4): D37.

[21] Vitry V., Delaunois F., Dumortier C. Mechanical properties and scratch test resistance of nickel-boron coated aluminium alloy after heat treatments[J]. Surface and Coatings Technology, 2008, 202(14): 3316-3324.

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