Научная статья на тему 'Numerical Simulation of Underwater Runoff Propagation in the Heraklean Peninsula Coastal Zone'

Numerical Simulation of Underwater Runoff Propagation in the Heraklean Peninsula Coastal Zone Текст научной статьи по специальности «Науки о Земле и смежные экологические науки»

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coastal zone of the Crimea / wastewater / underwater outlet / density stratification / numerical simulation

Аннотация научной статьи по наукам о Земле и смежным экологическим наукам, автор научной работы — V. A. Ivanov, V. V. Fomin

The problem of waste water propagation from the underwater source over the Heraklean Peninsula coastal zone is studied based on the three-dimensional numerical model simulating a break on the Sevastopol major municipal sewage trunk line. The calculations are made for three types of density stratification obtained by R/V Biryuza in September, 2015 and May, 2016. The outlet depth varied from 15 to 30 m. Numerical simulation was carried out on a uniform rectangular grid with 20 m horizontal step and 1 m vertical discreteness. Time integration step was 5 s, total integration time was 12 h. The effect of positive buoyancy in the model was created by fresh water inflow. It is revealed that the wastewater rising to the surface depends on the features of density stratification. The main factor preventing the polluted water from rising is the presence of the density drop layers above the outlet. The general trend consisting in increase of the polluted layer area accompanied by weakening of density stratification and decrease of current velocities is observed. It is found that the wastewater field close to the outlet consists of a stem and a jet oriented along the direction of the ambient current. As the current velocity increases, the top of the stem lowers and the jet sinks, its transverse size simultaneously decreases

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Текст научной работы на тему «Numerical Simulation of Underwater Runoff Propagation in the Heraklean Peninsula Coastal Zone»

Numerical Simulation of Underwater Runoff Propagation in the Heraklean Peninsula Coastal Zone

V.A. Ivanov, V.V. Fomin

Marine Hydrophysical Institute, Russian Academy of Sciences, Sevastopol, Russian Federation e-mail: vaivanov@inbox.ru, fomin.dntmm@gmail.com

The problem of waste water propagation from the underwater source over the Heraklean Peninsula coastal zone is studied based on the three-dimensional numerical model simulating a break on the Sevastopol major municipal sewage trunk line. The calculations are made for three types of density stratification obtained by R/V Biryuza in September, 2015 and May, 2016. The outlet depth varied from 15 to 30 m. Numerical simulation was carried out on a uniform rectangular grid with 20 m horizontal step and 1 m vertical discreteness. Time integration step was 5 s, total integration time was 12 h. The effect of positive buoyancy in the model was created by fresh water inflow. It is revealed that the wastewater rising to the surface depends on the features of density stratification. The main factor preventing the polluted water from rising is the presence of the density drop layers above the outlet. The general trend consisting in increase of the polluted layer area accompanied by weakening of density stratification and decrease of current velocities is observed. It is found that the wastewater field close to the outlet consists of a stem and a jet oriented along the direction of the ambient current. As the current velocity increases, the top of the stem lowers and the jet sinks, its transverse size simultaneously decreases

Keywords: coastal zone of the Crimea, wastewater, underwater outlet, density stratification, numerical simulation.

DOI: 10.22449/1573-160X-2016-6-82-95

© 2016, V.A. Ivanov, V.V. Fomin © 2016, Physical Oceanography

Introduction. One of the main sources of coastal water pollution is underwater runoffs from submerged sewers. To study the formation and propagation of discharged water field, the contact and remote observation methods [1 - 6], as well as physical and mathematical modeling, [1, 7 - 10] were applied.

Underwater outlets due to fresher water run into the sea provide a local positive buoyancy source at the bottom. It forms a stable system of turbulent currents in the form of stems and underwater jets. These current systems are commonly called plumes. Turbulent diffusion and advective transport cause the processes of the polluted water dilution in the plume. The dilution intensity (fold) is under the influence of the following factors: outlet type (point or distributed source in the form of a diffuser), water discharge in the source, dynamic conditions of the receiving environment, sea and wastewater density difference, etc. Rising from the outlet, the wastewaters may be delayed by density stratification on the neutral buoyancy horizon, which usually corresponds to the lower part of pycnocline, and propagate further under the pycnocline in the horizontal direction.

The current level of anthropogenic load on the coastal zone of Crimea is very significant [11]. Therefore, the study of the features of wastewater field formation and propagation off the Crimean coast is an important and relevant task.

The main diffuser of underwater wastewater outlet of Sevastopol is in the area of the Heraclean Peninsula Blue Bay 3 km away from the coast at 90 m depth.

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PHYSICAL OCEANOGRAPHY NO. 6 (2016)

Integrated field studies by R/V Biryuza in September, 2015 and May, 2016 revealed no traces of contamination just off the diffuser. At the same time a source of contamination was found above the sewage trunk line near the coast. It contains the chemical components typical of sewage waters, which form turbid layers at depths of 10 - 25 meters in this area. This source of pollution is likely the consequence of a break on the major municipal sewage trunk line. In this regard, it is of interest to find out the depth of the source location and types of density stratification under which the wastewater can rise into the surface sea layers.

The present article is aimed at mathematical modeling of the wastewater propagation over the Heraklean Peninsula coastal zone from the underwater source simulating a break on the Sevastopol major municipal sewage trunk line. Among the objectives of the work is a study of the features of the wastewater field spatial structure in the area of underwater outlet for the various types of density stratification and different velocity values of ambient currents, as well as determination of the conditions under which the wastewaters can rise to the sea surface.

Problem statement and governing equations. Introduce the Cartesian coordinate system (x, y, z), z axis is directed vertically. Consider a rectangular basin with a constant depth h0 . It is filled with continuously stratified fluid and limited by the liquid side boundaries.

At the initial time the three-dimensional thermohydrodynamic fields and the contaminant concentration field are described by the following conditions:

u = Uo, u = w = 0, n = 0, T = To(z), S = So(z), C = 0. (1)

Here u, v and w are the current velocity components along x, y and z axes correspondingly; U0 is the constant ambient velocity directed along x axis; n is the basin free surface coordinate; T and S are the water temperature and salinity; T0(z) is the ambient temperature distribution; S0(z) is the ambient salinity distribution; C is the contaminant concentration. To simplify the problem the impurity is assumed to be conservative.

At the time moment t > 0 at the point with coordinates (xp, yp, zp= - h0) at the bottom of the basin the local source simulating the wastewater discharge starts to act. The following parameters of the source are known: Qp is the water discharge; d is the horizontal size; wp = Qpjd2 is the water inflow velocity; Tp, Sp - inflow

water temperature and salinity; Cp is the impurity concentration at the source exit.

The aim is to study the evolution of the field of admixture caused by the action of a source for various types of T0(z) and S0(z) and different values of h0 and U0. To solve the problem, we use a numerical model of baroclinic water circulation [12, 13]. The model is based on three-dimensional o-coordinate equations of ocean dynamics in the Boussinesq approximation and hydrostatic equations of the following form (toting over repeated indices a and f3 from 1 to 2 is assumed):

d dn

—(Dua) + Au a + sapfDup + gD-^- + DBa = d t d x„

a

d _ x 5 ( km dua

dxp {Da + do[ D do J (2)

PHYSICAL OCEANOGRAPHY NO. 6 (2016) 83

^ + (DO + ^1 = 0,

d t d x„ da

d d —( DT ) + AT =— dt d x

f

dT

d X.

\

d ( KT dT

d d —(DS ) + AS = — dt d x

d d — (DC ) + AC = — dt d x

dS

d x„

dC d xa

+ - ,

da[ D da

+Af Ki_ dS

dai, D da

+Af Kc_ dC

da i D da

P = P(T, S ):

d

d

g

Ap = ~— (Du0ç>) + — (w*q>), Ba=^~

d x

da

T = 2 A dUa

rvrv - -^-^-A.

Po

id xa

u

D) pda' + a

dD

d x

P

a J

i

cxa

T a/3 = T Pa = AM

dup dun

+ -

dx„ dxr.

(4)

(5)

(6)

(7)

(8)

(9)

where (x1, x 2) = (x, y); a is the dimensionless vertical coordinate varying within -

1 to 0; D = h0 +n is the dynamic depth; zap are the turbulent stress tensor

components; AM, KM, AT, KT , AS, KS , AC, KC are the coefficients of turbulent viscosity and diffusion; g is the free fall acceleration; f is the Coriolis parameter; p0 is the mean water density; sa( = 0 where a = (; sl2 = -1; s2l = 1.

The unknown variables of the system (2) - (9) are: (u1, u2) = (u, v) - horizontal components of the velocity; w* is the current velocity component normal to the

surfaces a = const; p is the seawater density.

On the free surface (a = 0) the boundary conditions are as follows:

w = 0 Km dUa=0 KT_ dT = 0 Ks. dS=0 Kc dC = 0

* ' D da ' D da ' D da ' D da '

(10)

The boundary conditions at the bottom outside the source (a = -1, x 4- xp, y + yp) are:

Km dua

w = 0 M a

m KT dT n KS dS n KC dC n

= u\u\ua, —--= 0, —--= 0, —--= 0.

11 a D da D da D da

(11)

D da

where \ is the bottom friction coefficient; |u| =

The boundary conditions at the bottom in the source ( a = -1, x = xp, y = yp) can be written as [14]:

2 2 2 + u22

w„ = w„

KM dua

= \uua

(12)

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D da

PHYSICAL OCEANOGRAPHY NO. 6 (2016)

T

S

C

d

KT dT KS dS KC dC

wpT--T--= wpTp, wpS--S--= wpSp, wpC--C--= wpCp . (13)

p D do p p' p D do P p p D do P P

The coefficients of horizontal turbulent viscosity and diffusion are calculated using the Smagorinsky model [15]. To determine the coefficients of vertical turbulent viscosity and diffusion, Mellor - Yamada model is applied [12, 16].

Numerical algorithm for solving the system (2) - (13) is based on the splitting of tasks in the barotropic and baroclinic modes and the use of explicit schemes for horizontal coordinates and implicit schemes for the o-coordinate. To approximate the advective operators A in (2), (4) - (6) TVD schemes are applied [17, 18]. These schemes are monotonic, which is a required condition for adequate modeling of the fields with high spatial gradients. Detailed description of the numerical model algorithm is given in [12].

Numerical experiments and results discussion. Numerical experiments were conducted for a square pool of 2 km and a depth of h0. The source coordinates were (xp, yp, zp) = (600 m, 1000 m, -h0) and its horizontal dimension was d = 20 m. The nominal water discharge at the source was Qp = 1.4 m3/s and the impurity concentration therein was Cp = 500 mg/l. We assumed that the inflowing water had zero salinity (Sp = 0), and its temperature was equal to that of the environment, i. e. Tp = T0 (-h0). Thus, the positive buoyancy effect was created in the underwater source due to fresh water inflow.

For the problem under consideration, the Froude number has the form Fr = wj, where g' = g (pb - pp )jpb , pp is water density in the source, pb is

water density around the source. Under the accepted values of Qp and d the magnitude Fr is about 0.01. This means that in the given statement of the problem the effect of buoyancy is predominant.

Numerical simulation was carried out on a uniform rectangular grid with a horizontal step d and 1 m vertical discreteness. Time integration step was 5 s, total integration time was 12 h. During the first hour of model time the water discharge in the source was linearly increased within 0 - 1.4 m3/s and further remained unchanged. The boundary conditions at x = 0 are given as (1). On the other liquid boundaries the zero-gradient conditions [12, 14] were used, which is acceptable in the calculations for short periods of time.

The bottom friction coefficient in the boundary conditions (11) and (12) was defined by the formula u = 0,16/ln2(Jz/zb) where 8z is the vertical distance from the bottom up to the point where the friction coefficient is determined; zb = 0.01 m is the bottom surface roughness parameter. Calculations were carried out with zero Coriolis parameter. Equation of the seawater state (7) was defined by the UNESCO formula.

Density stratification on September, 9 - 10, 2015. In the first cycle of numerical experiments the profiles shown in Fig. 1 a, b were used as T0(z) and S0(z). Solid black curves correspond to the hydrological situation in September 9, 2015 (hereinafter - the first type of stratification); dashed black curves correspond to the hydrological situation in September 10, 2015 (hereinafter - the second type of stratification). These profiles are obtained by averaging over the ensemble of the

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85

stations that have been most closely located to the underwater runoff pipeline. As one can see, the profiles are markedly different from each other only in the upper 30 m layer. Analysis of the Brunt-Vâisâlâ frequency profiles N indicates that the highest water density gradients for both types of stratification are located in a layer of 15 - 30 m (Fig. 1, c). The mean value of N in 0 - 30 m layer for each type of profiles is equal to 18.3 and 13.1 cycles/hour, respectively.

Fig. 1. Water temperature, salinity and Brunt-Vaisala frequency profiles in the area of the underwater outlet for three hydrological stations: solid black curves - Sept. 9, 2015; dotted black curves - Sept. 10, 2015; solid grey curves May, 20, 2016

The list of numerical experiments for the first and second types of stratification with different values U0 and h0 is given in Tab. 1. Selection of U0 values is based on the results of ^.DCP-measurements in the Heraclean Peninsula area in the autumn of 2015 [19]. According to this data the mean current velocities were ~ 0.05 m/s during the observation period.

The main object of the research was the field of the c impurity concentration, normalized by the amount of the impurity concentration in the source C:

c(x, y, z, t) = 100 %C(x,y, z, t)/C(Xp,yp ,-h0, t). (14)

To identify areas of contamination (plume boundaries) a threshold value c = = 5 % was applied. The total area of contamination in each estimated layer with the thickness of zk+1 - zk was estimated by the following formula:

V (zk+12, t) = 2 Y( X, yi, zk+12, t), (15)

i

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PHYSICAL OCEANOGRAPHY NO. 6 (2016)

Y( X, yi, zk+12, t) =

\b, c( x, y}, zk^ t) > 5%:

"V2'"' [0, c(X-,yj, z^+V2, t) < 5%,

where k is the horizon number; zk= (zk+1 + zk)/2 is the vertical coordinate of cell center; xh yj are horizontal coordinates of the difference grid; b = d2 is the area of the horizontal section of the cell. From (15) it is clear that V(zkt)jb is the total amount of cells in estimated layer zk+1 - zk , for which c > 5 %.

T a b l e 1

Maximum Areas of Contaminated Zones (maxF) and Their Depth (zmax) for the First and Second Type of Stratification (TS) under Various Values of U0 and h0

h0, m

U0, m/s

TS

maxV, km2

m

h0, m

U0, m/s

TS

maxV, km2

15 0.025 1 0.52 5.5 15 0.025 2 3.54 0.5

15 0.050 1 0.28 9.5 15 0.050 2 2.69 0.5

15 0.075 1 0.37 14.5 15 0.075 2 0.05 0.5

20 0.025 1 0.47 11.5 20 0.025 2 2.25 0.5

20 0.050 1 0.31 13.5 20 0.050 2 0.85 0.5

20 0.075 1 0.25 18.5 20 0.075 2 0.01 1.5

25 0.025 1 0.40 18.5 25 0.025 2 0.35 13.5

25 0.050 1 0.29 19.5 25 0.050 2 0.21 16.5

25 0.075 1 0,42 19.5 25 0.075 2 0.26 21.5

30 0.025 1 0.37 20.5 30 0.025 2 0.33 23.5

30 0.050 1 0.28 22.5 30 0.050 2 0.29 24.5

30 0.075 1 0.37 22.5 30 0.075 2 0.37 22.5

z

The curves in Fig. 2 - 6 provide some insight into vertical distribution of the contaminated zones with different combinations of parameters h0 and U0.

Fig. 2 shows the V/b distribution of the source at depth h0 = 15 m for the first and second types of stratification and three values of U0. The curves correspond to the time point t = 12 h. Under the first type of stratification the major contaminated zones are at a depth of 5 m and more (Fig. 2, a). It is due to the presence of the local density jump in the layer of 5 - 7 m (Fig. 1, c). Position of contaminated zones and their areas is largely affected by the velocity of ambient currents. Thus,

PHYSICAL OCEANOGRAPHY NO. 6 (2016)

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with increasing of U0 from 0.025 to 0.075 m/s the zones become lower by 5 m to the bottom simultaneously decreasing their areas by 1.5 - 2 times.

v/h v/b

o 2oo 4oq 600 800 1000 1200 1400 o 2000 4000 sooo a 000 10000

Fig. 2. Distribution of the contaminated zone in the vertical direction where h0 = 15 m for the first (a) and second (b) types of stratification where t = 12 h. Solid black curves - V/b where U0 = = 0.025 m/s; dashed gray curves - V/b where U0 = 0.050 m/s; solid gray curves - V/b where U0 = = 0.075 m/s

The vertical structure of contaminated zones for the second type of stratification (Fig. 2, b) differs from the case discussed above. Due to weak stratification in 0 - 20 m layer (Fig. 1, c), polluted waters reach the basin surface and spread all over it in a 1 - 2 m thickness layer. When U0 = 0,075 m/s the contamination area of the basin surface is two orders less than when U0 = = 0.025 m/s and U0 = 0.05 m/s.

Fig. 3. Distribution of the contaminated zone in the vertical direction where h0 = 20 m for the first (a) and second (b) types of stratification where t = 12 h. Colors and type of curves have the same match as in Fig. 2

88 PHYSICAL OCEANOGRAPHY NO. 6 (2016)

Fig. 4 shows the distribution of V/b for h0 = 25 m. In the first type of stratification under all values of U0 the zones of contaminated waters are concentrated in the layer of ~15 - 22 m (Fig. 4, a). In the second type of stratification, the position of these zones depends on velocity of the ambient currents. Thus, the increase of U0 from 0.025 to 0.075 m/s deepens the zones from 13 to 22 m.

Fig. 4. Distribution of the contaminated zone in the vertical direction where h0 = 25 m for the first (a) and second (b) types of stratification where t = 12 h. Colors and type of curves have the same match as in Fig. 2

Fig. 5. Distribution of the contaminated zone in the vertical direction where h0 = 30 m for the first (a) and second (b) types of stratification where t = 12 h. Colors and type of curves have the same match as in Fig. 2

PHYSICAL OCEANOGRAPHY NO. 6 (2016)

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Fig. 5 demonstrates the distribution of V/b for h0 = 30 m (the source is located under the density jump for both types of stratification). In this case, the ambient currents have no appreciable effect on the position of the layers of contaminated water. As for the first and second type of stratification, the basic zones of contamination are concentrated in the layer of ~ 18 - 27 m.

Tab. 1 shows the maxima values of the areas of contaminated zones (maxV) and their respective horizons (zmax) for 24 combinations of the problem parameters. Apparently, by varying U0 and h0, the area of contaminated zones varies from 0.01 to 3.5 km2. The general trend is that when vertical gradients of density and current velocity decrease, contamination area expands. MaxV mean values for the first and second types of stratification are 0.36 and 0.93 km2, respectively. In the second type of stratification the more favorable conditions for the penetration of contaminated water into the sea surface layers (in 6 of 12 cases zones of maximum contamination are located in the upper 2 m layer) appear.

Density stratification on May 20, 2016. In the second cycle of numerical experiments (Tab. 2), the profiles T0(z) and S0(z) were applied. They are shown in Fig. 1 by solid gray lines (hereinafter - the third type of stratification). These profiles are based on the sensing data over the underwater outlet pipeline at the station with the depth of ~30 m. Such type of profiles, as compared with those described above, is characterized by weak stratification. (Mean value N in 0 - 30 m layer is 7.3 cycle/hour). This case is of a particular interest, since it was this station where the ~ 100 - 200 m surface plume of polluted water was visually observed.

T a b l e 2

Maximum Areas of the Contaminated Zones (maxF) and Their Depth (zmax) and Surface Anomalies T and S for the Third Type of Stratification under Various Values of U0

h0, m U0, m/s maxV, km2 zmax, m ÔT, °C ÔS, %

30 0.010 0.83 7.5 -1.05 -0.12

30 0.025 0.85 7.5 -0.78 -0.08

30 0.050 0.41 8.5 -0.22 -0.01

30 0.075 0.30 13.5 -0.02 0.01

Fig. 6 illustrates the third type of stratification the V/b distribution where h0 = = 30 m and three values of U0. The curves correspond to the time point t = 12 h. It is shown that when U0 = 0.025 m/s the layer of 6 - 10 m is exposed to the maximal contamination. When U0 equals to 0.050 and 0.075 m/s the contaminated areas decrease by more than 2 times, as compared with the case when U0 = 0.025 m/s.

It was found that other, less marked layers can appear below the main layer of pollution. Thus, when U0 = 0.075 m/s, the layers of 12 - 15 and 20 - 22 m turn to be more contaminated. This vertical splitting of the wastewater into several layers is a rather typical phenomenon for the Crimean coastal waters [2]. 90 PHYSICAL OCEANOGRAPHY NO. 6 (2016)

0.0 2.5 5.0 7,5 10.0 E 12.5

£ 17.5 20.0 22.5 25.0 27.5 30.0

Fig. 6. Distribution of the contaminated zone in the vertical direction where h0 = 30 m for the third type of stratification where t = 12 h. Colors and type of curves have the same match as in Fig. 2

According to Tab. 2, the areas of contamination zones of the third type of stratification are ~0.6 km2 on average with the mean location depth of ~9.3 m.

Vertical structure of the contaminated water field for the third type of stratification is demonstrated in Fig. 7. Here one can see the function isolines where t = 12 h for three values of U0. The dimensionless magnitude x/d is plotted along the horizontal coordinate. Peculiarities of the considered fields are the stem rising from the underwater outlet and the jet oriented along the direction of the ambient current. With the current velocity increase, the stem top is lowered and the jet is elongated in the longitudinal direction and is vertically compressed by penetration at the upper boundary of ~5 m.

The simulation results showed that, according to the criterion c > 5%, the jet cross-scale at 1 km distance of 1 from the source can reach ~ 500 m where U0 = = 0.025 m/s and 250 - 200 m at the other two values of U0. Appearance of the contaminated water jet on the six characteristic horizons where U0 = 0.050 m/s is shown in Fig. 8. The jet is clearly seen in 7.5 - 9.5 m layer, it has a transverse dimension of ~200 m. Outside this layer the jet sharply narrows up to 50 m or less.

Identification of underwater jets is usually made on the basis of a series of vertical probings perpendicular to the direction of the jet propagation [2]. With small transverse dimensions such method does not exclude skipping of the axial section of the jet, which probably happened on May, 20, 2016 in the measurement of water turbidity in the area of the underwater outlet.

Next evaluate the magnitudes of surface temperature and salinity anomalies using the following relations:

ST = T (xp, yp,0, t) - 70(0), SS = S (Xp, yp,0, t) - S0 (0), (16)

where the overbar denotes averaging over a period of 12 h.

V/b

0 400 800 1200 1600 2000 2400

_ 1__

/. 1 /

(i V I n

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Fig. 7. Isolines of the function c(x,y,z,t = 12h) for the third type of stratification: a - where U0 = 0.025 m/s; b - where U0 = 0,050 m/s; b - where U0 = 0,075 m/s

Calculations by the formulas (16) show that there are negative temperature and salinity anomalies generated right above the wastewater source (Tab. 2). Their values depend on the velocity of ambient currents. When U0 = 0.025 m/s the value of the temperature anomalies reaches - 1°C, that of salinity anomalies -0,1 %.

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PHYSICAL OCEANOGRAPHY NO. 6 (2016)

Fig. 8. Isolines of the function c( x, y, zk+y2,t = 12h) for the third type of stratification where U0 = = 0,050 m/s and at various values of k

Conclusion. The article concerns the problem of wastewater propagation over the Heraklean Peninsula coastal zone from the underwater source simulating a break on the Sevastopol major municipal sewage pipeline.

On the basis of the three-dimensional numerical model the calculations of initial stages of wastewater propagation for three types of density stratification obtained by R/V Biryuza in September, 2015 and May, 2016, were carried out. The water discharge in the source was 1.4 m3/s. The effect of positive buoyancy in the model was created by fresh water inflow. The outlet depth h0 ranged from 15 -30 m, the ambient current velocity U0 was in the range of 0.025 - 0.075 m/s.

Analysis of the simulation results showed that the outlet of contaminated water to the surface depends on both the characteristics of density stratification and on U0 and h0 values. The main factor impeding the contaminated water rise is the presence of layers with density jumps above the source.

The general trend is that when vertical gradients of density and current velocity decrease, contamination area expands. The area of contaminated water areas varies between 0.4 - 0.9 km2.

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Wastewater field near the source consists of the stem rising from an underwater outlet and the jet oriented along the direction of the ambient current. As U0 increases, the top of the stem lowers and the jet sinks, its transverse size simultaneously decreases. In some cases the wastewater field splits vertically into two layers.

On the water surface above the source the negative anomalies of temperature and salinity are formed. They reach -1°C and -0.1 %o, respectively.

The results can be used for interpretation and planning of field experiments on the wastewater propagation in the area of the Crimean Peninsula.

Acknowledgements. The research was carried out under the sponsorship of the Ministry of Education and Sciences of the Russian Federation within the framework of the Federal Target Program "Research and Development in Priority Development Directions of the scientific-technological complex in the Russian Federation 2014 - 2020" (unique project code RFMEFI57714X0110).

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