CC BY
17
ФИЗИКА PHYSICS
УДК 669.018.6 ББК 34.25 D 78
Dovchinvanchig Maashaa
PhD, School of Engineering and Technology, Mongolia University of Life Sciences, Ulaanbaatar, Mongolia, email: Dovchinvanchig@muls.edu.mn Tsendsuren Balgan
PhD, School of Engineering and Technology, Mongolia University of Life Sciences, Ulaanbaatar, Mongolia, email: tsendsuren_balgan@yahoo.com
Zhao Chun Wang
PhD, College of Arts and Sciences, Shanghai Maritime University, Shanghai Shi, Shanghai, China
Microstructure and martensitic transformationof Ni50Ti47Nd3
shape memory alloy
(Peer-reviewed)
Abstract. The phase transformation and microstructure behavior of Ni50Ti47Nd3 shape memory alloy was investigated by scanning electron microscope, X-ray diffraction and differential scanning calorimetry. The results showed that the microstructure of Ni-Ti-Nd ternary alloy consists of the NiNd phase and the NiTi matrix phase. One-step phase transformation was observed alloy.
Keywords: Ni-Ti-Nd shape memory alloy, microstructure, martensitic transformation.
Довчинванчиг Маашаа
Кандидат наук, Школа инжиниринга и технологий, Монгольский университет наук о жизни, Улан-Батор, Монголия, e-mail: Dovchinvanchig@muls.edu.mn Цендсурен Балган
Кандидат наук, Школа инжиниринга и технологий, Монгольский университет наук о жизни, Улан-Батор, Монголия, e-mail: tsendsuren_balgan@yahoo.com
Чжао Чунь Ван
Кандидат наук, Колледж искусств и наук, Шанхайский морской университет, Шанхай Ши, Шанхай, Китай
Микроструктура и мартенситное превращение сплава состава Ni50Ti47Nd3 с памятью формы
Аннотация. Методами сканирующей электронной микроскопии, дифракции рентгеновских лучей и дифференциальной сканирующей калориметрии исследованы фазовое превращение и поведение микроструктуры сплава Ni50Ti47Nd3 с памятью. Результаты показали, что микроструктура троичного сплава Ni-Ti-Nd состоит из фазы NiNd и матричной фазы NiTi. Наблюдалось пошаговое фазовое превращение сплава.
Ключевые слова: сплав Ni-Ti-Nd, обладающий памятью формы, микроструктура, мартенситное превращение.
Introduction
Ni-Ti based shape memory alloys (SMAs) are very important materials becauseof unique shape memory effect and super-elasticity behavior. Today this kind of material is used in many different fields, especially in engineering and medical application. Current research interest on SMA are mainly controlling the martensitic transformation temperature and improving the shape memory effect for their applications. The effect of martensitic transformation, super-elasticity and shape memory effect have been studied widely by adding transitional elements to Ni-Ti binary alloys which include Fe, Nb, Hf, Zr, Pd, Pt etc. Among them, Fe and Nb have been added to Ni-Ti binary alloys, which decrease the martensitic transformation temperature. But Hf, Zr, Pd and Pt
addition can increase the martensitic transformation temperature of Ni-Ti alloys.
Moreover, the microstructure and martensitic transformation temperature of the Ni-Ti binary alloys have also been studied using scanning electron microscopy (SEM), energy dispersive spectrometry (EDS), X-ray diffraction (XRD), and differential scanning calorimetry (DSC). The Ni-Ti binary alloys were found to decrease and increase the phase transformation temperature and change the phase transformation sequence.
Rare-earth element Nd is also a widely used element, particularly in magnetic materials. However, only few studies have been conducted on Nd addition to a shape memory alloy. The only study found in the literature is that on Nd addition to Ni-Ti-Fe alloy, but the Nd fraction is less than 1%. The effect of Nd addition to Ni-Ti binary alloy on microstructure and phase transformation temperature remains unclear.
In this paper Nd content with atomic fraction of 3% added to Ni-Ti binary alloys, and the microstructure and martensitic transformation are studied experimentally.
1. Experimental methods
The Ni50Ti47Nd3 alloy were prepared by melting each 10g of raw materials with different nominal compositions (99,9 mass% sponge Ti, 99,7 mass% electrolytic and 99,95 mass% Nd) in a nonconsumable arc-melting furnace using a water-cooled copper crucible. The alloy in denoted Ni50Ti47Nd3 alloy. Melting was repeated four times to ensure the uniformity of composition. The specimens are spark-cut from the ingots and solution - treated at 850°C for an hour in a quartz tube furnace. Subsequently the specimens were quenched using water. Thereafter, the specimens are mechanically and lightly polished to obtain a plain surface.
The phase transformation temperature of Ni50Ti47Nd3 alloy was determined by DSC using a TA Q2000 calorimeter. The temperature range of heating and cooling was from -30°C to 155°C, and the scanning rate of heating and cooling was 10°C/min. SEM observations were conducted using a FEI Quanta 650 FEG equipped with EDS analysis systems made by Oxford. An XRD experiment was conducted using a D/MAX-2500PC X-ray diffractometer.
2. Results and discussion
2.1. Microstructure of Ni50Ti4^7Nd3 alloy
Fig. 1 depicts the back-scattering SEM images of Ni50Ti47Nd3 alloy. There are two different morphologies, namely, white phase and matrix can be identified in the SEM image. The white phase is in irregular shape and distributed randomly in the matrix.
Fig. 1. Back-scattering SEM image Ni5oTi47Nd3
To identify the phase structure, EDS analysis was conducted in SEM. The compositions of Ni-Ti-Nd alloy are shown in Table 1. The Ti: Ni ratio in the matrix of all Ni-Ti alloy is measured to be near 1. Thus, the matrix can concluded to be NiTi phase. The Nd: Ni ratio in the white phase of Ni-Nd alloy is measured to be near 1:1. It was foundby XRD analysis, that there is a
NiTi phase. Thus, the white phase can be concluded to be NiNd.
Table 1
Composition of Ni-Ti-Nd alloy
Ti (at. %) Ni (at. %) Nd (at. %)
NisoTi47Nd3 Matrix 49,24 50,21 0,55
White phase 2,97 49,84 47,19
2.2. XRD analysis of Ni50Ti47Nd3 alloy
Fig. 2 depicts the XRD curve of Ni50Ti47Nd3 alloy at room temperature. The diffraction peaks are identified to be from NiTi B19' phase andNiNd phase alloy after comparing with JCPDF cards (numbers 65-0145 and 19-0818). The detailed crystal plane indices are marked in Fig. 1 for the relative intensities of each XRD curveare quite different because of the differences in NiTi phase fraction and NiNd phase fraction. In this paper, the letter NiTiM denotes the NiTi B19' phase. This perspective will be confirmed in the following DSC analysis.
2th eta(deg)
Fig. 2. XRD curve of NisoTL^Nd
The lattice parameters of alloy can be also calculated by peaks position in XRD curve and in Table 2 it is shown clearly that cell volume V expand for either Ni-Ti-Nd ternary alloy. The observation can also be confirmed in the following composition analysis.
Table 2
Lattice parameters of Ni50Ti47Nd3 alloy
Alloy Phase a (nm) b (nm) c (nm) ß (°) V (nm3)
Ni50Tl47Nd3 M 0,2939 0,4124 0,4639 98,39 0,05562
2.3. Phase transformation of Nis0Ti50 alloy
Fig. 3 depicts the DSC curves of the Ni50Ti47Nd3 alloy. Each DSC curve of Ni50Ti47Nd3 shows only one peak during the heating and cooling process, which indicates a one-step B2^B19' phase transformation. The effect of Ni-Ti concentration on martensitic transformation start temperature Ms. For Ni-Ti alloy, the Ms is measured to be 77,44°C. For example, Liu et al. [1] measured the Ms to be about -50°C for Ni50,7Ti49,3 alloy after annealing at 900°C for 60 min. Tabish et al. [2] measured the Ms to be -22,12°C for №50^50 alloy after annealing at 1000°C
for 120 min. Wasilewski et al. [3] measured the Ms to be 65°C for Ni49,8Ti50,2 lloy. In this work, the composition of the matrix in measured to be Ni49,36Ti50,64, which is Ti-rich. So, a high Ms of Ti-Ni binary alloy is reasonable. Again, the martensitic transformations finish temperature Mf in NiTi alloy is higher than room temperature of 20°C. Thus, the martensitic transformations have been finished at room temperature and the Ni-Ti-Nd alloy should be in total martensitic phase, which is in agreement with the XRD results.
Temperature С
Fig. 3. DSC curve of Ni5oTi47Nd3
3. Conclusions
In summary, the microstructure and martensitic transformation behavior was investigated by XRD, SEM and DSC. The microstructure of the Ni50Ti47Nd3 alloy consists of NiNd alloy and NiTi matrix. The lattice parameters of Ni50Ti47Nd3 matrix are a=0,2939 nm, b=0,4124 nm, c=0,4639 nm. The Ni-Ti-Nd alloy has a one-step phase transformation.
References:
1. TiNiPd thin film microvalve for high temperature applications / Y. Liu, M. Kohl, K. Okutsu [et al.] // Mat. Sci. Eng. A. 2004. Vol. 378, No. 1-2. P.205-209.
2. Development and characterization of Ni50Ti50 shape memory alloy used for biomedical applications / T.A. Tabish, S. Atiq, M. Ali, A.N. Ch, Z.U. Reham, T.Z. Butt // Int. J. Chem. Mater. Sci. Eng. 2013. Vol. 7, No. 12. P. 92-93.
3. Wasilewski R.J., Butler S.R., Hanlon J.E. On the Martensitic Transformation in TiNi // Met. Sci. J. 1967. Vol. 1. P. 104-110.
Примечания:
1. TiNiPd thin film microvalve for high temperature applications / Y. Liu, M. Kohl, K. Okutsu [et al.] // Mat. Sci. Eng. A. 2004. Vol. 378, No. 1-2. P.205-209.
2. Development and characterization of Ni50Ti50 shape memory alloy used for biomedical applications / T.A. Tabish, S. Atiq, M. Ali, A.N. Ch, Z.U. Reham, T.Z. Butt // Int. J. Chem. Mater. Sci. Eng. 2013. Vol. 7, No. 12. P. 92-93.
3. Wasilewski R.J., Butler S.R., Hanlon J.E. On the Martensitic Transformation in TiNi // Met. Sci. J. 1967. Vol. 1. P. 104-110.
