CC BY
2INCREASING REGENERATION EFFICIENCY BY RECYCLING
ALKANOLAMINES
Rakhimov Ganisher
Karshi Engineering-Economics Institute, Uzbekistan
Abstract. This article aims to improve the efficiency of the gas purification process by determining the composition of the used alkanolamine solutions and regenerating them using the absorption method of gas purification from sour components. Keywords: alkanolamine, monoethanolamine, diethanolamine, absorbent, desorption, ion exchange, filter, regeneration.
Аннотация. Целью данной статьи является повышение эффективности процесса очистки газов путем определения состава используемых растворов алканоламинов и их регенерации с использованием абсорбционного метода очистки газов от кислых компонентов.
Ключевые слова: алканоламин, моноэтаноламин, диэтаноламин, абсорбент, десорбция, ионный обмен, фильтр, регенерация.
Annotatsiya. Ushbu maqolada gazlarni nordon komponentlardan absorbsiya usulida tozalash texnologiyasi ishlatiladigan alkanolamin eritmalarini ishlatilgan alkanolamin eritmalarini tarkibini aniqlash va ularni kombinatsiya usulida qayta tiklash orqali gazlarni tozalash jarayonini samaradorligini oshirishga qaratilgan. Kalit so'zlar: alkanolamin, monoetanolamin, dietanolamin, absorbent, desorbsiya, ion almashinish, filtr, regeneratsiya.
Каршинский инженерно-экономический институт, Узбекистан
Qarshi muhandislik iqtisodiyot instituti, O 'zbekiston
doi: https://doi.org/10.5281/zenodo.10358168
www.srt-iournal.uz
Introduction. Let's consider one of the first processes carried out at Gas processing plant - the process of cleaning gas from sour compounds (harmful gases). Among the sour compounds in hydrocarbon raw materials, the most common aggressive and corrosive "harmful substances" are sulfur compounds, which include hydrogen sulfide and carbon dioxide, which reduce the heat of combustion of hydrocarbon gas.
Purification of hydrogen sulfide and carbon dioxide compounds with aqueous solutions of amines is the most widely used method with a history of more than fifty years. The most commonly used absorbent liquids used in the gas purification process from H2S and CO2 are (absorbent) ethanolamines: monoethanolamine (MEA), diethanolamine (DEA), triethanolamine (TEA), diglycolamine DGA), disopro-panolamine (DIPA), methyldiethanolamine (MDEA). When ethanolamines interact with acidic compounds in the gas, they form chemical compounds, which are easily regenerated when the temperature rises and the pressure decreases.
Literature analysis and methods. Correct selection of the absorber is the main task in cleaning natural gas from H2S, COS, CS2, RSH. The correct selection of the absorber not only increases the quality of the product gas, but also reduces the energy and metal consumption of the equipment and helps to protect the environment in gas processing plants.
Despite the variety of gas purification
methods, the absorber must meet stable
general requirements: the absorber must
have a high absorption capacity of acidic
components, despite their content in the gas
being in a large interval; the partial pressure
of the absorber should be low, because its
doi: https://doi.org/10.5281/zenodo.10358168 GEOLOGIYA VA NEFT-GAZ SANOATI ГЕОЛОГИЯ И НЕФТЕГАЗОВАЯ ПРОМЫШЛЕННОСТЬ GEOLOGY AND OIL-GAS INDUSTRY
loss in the process is reduced; for good contact with gas, the viscosity of the absorbent should be low; should be insoluble in hydrocarbons; should be neutral to hydrocarbons and inhibitors; low corrosion activity; resistant to oxidation and thermal decomposition; do not react with various compounds; stable to the formation of foam; the boiling point of the absorber should be lower than that of all components.It should be noted that the presence of polyethylene polyamines in the composition of the used alkanolamines increases the viscosity and foaming properties of the solutions along with extinguishing the operational activity of absorbents.For this reason, it is necessary to separate the thermal degradation products of amine from the maximum solution composition.
The combined recovery of alkanolamines was carried out using MDEA and DEA solutions over bentanite, followed by activated carbon and ionite. Although the technology of this method is expensive, it is considered highly effective:
Experiment 1. A column with a diameter of 20 mm and a height of 200 mm is filled with ampholyte in a volume of 100 cm3 (by the length of the column ~ 5 cm) and a pre-measured amount (50-100 g) of DEA is added using a dropper.
The time of the procedure is 1-1,5 hours. There was no significant change in the color of the DEA solution passing through the column.
Experiment2. This experiment is carried out in a column with a diameter of 20 mm and a height of 200 mm, in accordance with the experiment 1, but instead, ampholyte is replaced with activated carbon in the volume of 100 cm3 (by the length of the column ~ 5 cm). The procedure takes 1 -
1,5 hours. The color of the DEA solution passing through the column becomes clear.
Experiment 3. This experiment is also carried out under the conditions of experiments 1 and 2, replacing ampholyte and/or activated carbon, bentonite.The procedure takes 3 - 3,5 hours. The color of the DEA solution that has passed through the column becomes transparent.
Experiment 4. Both are carried in a glass column with a diameter of 20 mm and a length of200 mm. Activated carbon with a layer height of 6 - 6,5 cm and ampholyte is placed at the same height.Alkanolamine is
added dropwise.The passage time of
alkanolamines is 2-3 hours.
Experiment 5. Bentonite, activated
carbon and ampholyte were added to a
vacuum column with a diameter of 20 mm
in an orderly manner, using filter papers as a
doi: https://doi.org/10.5281/zenodo.10358168 GEOLOGIYA VA NEFT-GAZ SANOATI ГЕОЛОГИЯ И НЕФТЕГАЗОВАЯ ПРОМЫШЛЕННОСТЬ GEOLOGY AND OIL-GAS INDUSTRY
barrier, and 100 cm3 of bentonite cleaned from the amorphous part.From the top of the column, a pre-measured (50 or 100 g) used DEA solution is dripped using a dropping funnel, and a receiving container is installed in the lower part.
Results. The used DEA working solution was completely analyzed by the combined method based on ionization and thermal methods.
From the results of the analysis, we can see a decrease in the amount of Na, Mg, K, Ca, Fe elements in the DEA working solution (table 1).
Table 1
The obtained data of table 2 shows that the working concentration of recycled ethanolamines decreases to 22% after purification, and it is recommended to compensate the lost amount by adding additional new absorbent to the system.
Analysis results of purified technical DEA solution
The composition of the used DEA solution According to the norm Amount in solution, % Amount after cleaning
Free DEA, % 30 22,37 22,0
Piperazine, % 4,0 3,0 3,0
Iron, mg/l 10,0-15,0 315 7,0-9,0
Bound DEA (tarnish substances), g/l 0,5-1,0 7,6 0,5-0,7
Heat resistant salts, % 0 5,2 0,02-0,03
Sodium (Na+) salts, mg/l 0 63,1 0,01-0,02
Potassium (K+) salts, mg/l 0 13,7 0,01-0,02
Formic acid, mg/l 50,0 667,3 36-41
Precipitableparticles, mg/l 50,0 93 6.7
The reduction of heat-stable salts in the regenerated alkanolamines from 5,2 % to 0,03 % proves that the combined process is effective while preventing foaming of the reagent in the system.
The amount of bound DEA (tar-like substances) in the working solutions of the absorbent has decreased from 7,6 g/l to the minimum concentration of 0,5 - 0,7 g/l, the amount of various additives should not exceed 1% in the normal operation of gas cleaning devices.
working properties of the purified DEA working solution also change dramatically, including:if the foamability of the solution approaches the norm and is equal to 2,3 cm/min, the stability of the foam (13 sec.) fully corresponds to the established norms, which is due to the reduction of surfactants that create stable foam in the solution, and the reduction of the surface tension coefficient caused by these substances at the same time, it allows to prevent the destruction of alkanolamines, which is
Table 2
Analysis ofphysico-chemical and working properties of purified technical DEA
solution
Physical and chemical properties Indicators of 30% (pure) DEA aqueous solution Indicators of a 30% aqueous solution of technical DEA obtained by the ion exchange method
pH of the solution 10,8 10,4
Viscosity, sPz 2,6 2,8
Surface tension, din/cm 71,65 71,35
Absorptionvolume, mol/mol 0,40-0,44 0,40-0,44
Selectivityna H2S, CO2, % 95,0 95,0
Effervescence, cm/min 2,2 2,3
Foam stability, sec. 13 13
Amount of amine 21,4 21,3
From the analytical data in Table 2, it
can be seen that the physicochemical and
doi: https://doi.org/10.5281/zenodo.10358168 GEOLOGIYA VA NEFT-GAZ SANOATI ГЕОЛОГИЯ И НЕФТЕГАЗОВАЯ ПРОМЫШЛЕННОСТЬ GEOLOGY AND OIL-GAS INDUSTRY
intended for reuse.
At the same time, it is observed that the
selectivity of the DEA working solution in terms of environmental pH, absorption volume of hydrogen sulfide and carbon dioxide is also restored, only the reduction
of the amount of amine can be observed, and it is recommended to eliminate this problem by adding unused absorbents.
Conclusion. The composition of
Table 3
Indicators of suspension cleaning in the method of ionization of DEA working
solution
Composition of the used DEA solution Unit of measure DEA working solution 3-stage purified solution
Free DEA, % 23,07 23,0
Bound DEA (Tarminous Substances) % 6,93 0,5-0,7
Heat resistant salts % 5,2 0,02-0,03
Amino acids ppm 4233 92-97
Glycoliates ppm 627 81-86
Acetates ppm 439 73-79
Let them go ppm 1648 102-108
Oxalate ppm 498 112-116
Iron mg/l 118 7,0-9,0
Precipitated particles mg/l 93 6,7
Mechanical compounds mg/m3 779-1099 179-189
Sulfur preservatives % 2,4-2,8 2,4-2,8
Resin compounds % 2,5-3,5 2,5-3,5
Hydrates % 3,5-4,0 3,5-4,0
H2S mg/m3 15-17 15-17
CO2 % 2,1 2,1
Sodium (Na+) salts, mg/l 63,1 0,01-0,02
Potassium (K+) salts, mg/l 13,7 0,01-0,02
Formic acid, mg/l mg/l 667,3 36-41
doi: https://doi.org/10.5281/zenodo.10358168
working ethanolamine solutions used in the purification of natural gases from sour components using alkanolamines was determined.
Using the combination method, the content additives affecting the operational properties of the used alkanolamines are
based on the reduction of the amount of thermally stable salts, free elements, heavy organic substances, the physico-chemical properties of the purified alkanolamines affecting the operational properties, viscosity and foaming, surface tension are determined and reused.
REFERENCES
1. N.A. Igamkulova, Sh.Sh. Mengliev, T.B. Turaev, Kh.N. Rakhimov, Kh.L. Polatov. Restoring the working properties of used ethanolamines and reducing their impact on the environment // Composite Materials Scientific-technical and practical magazine #2/2021 Tashkent-2021 247-251 p.
2. Manovyan, A.K. Technology of primary processing of oil and natural gas Text.: uchebnoe posobie dlya vuzov. - Izd. 2-e - M.: Khimiya, 2001. - 568 p.
3. Technology for processing natural gas and condensate Text.: Reference book: V 2 ch. M.: OOO "Nedra-Biznestsentr", 2002. - Ch. 1. - 517 p.
4. R.L. Shklyar, A.V. Mamaev, S.A. Sirotin. Non-selective absorption of kislykh gasov vodnym rastvorom methyldiethanolamine. Journal of Engineering and Technological Sciences 48 (2): 2011. p.231-241.
5. Kh.N. Rakhimov, T.B. Turaev, F.O'.Shapatov.Analysis of the process of destruction of ethanolamines used in gas cleaning plants. // "Innovations in the oil and gas industry, modern energy and its problems" Materials of the 2nd international conference Tashkent-2021 71-72 p.
6. Kh.N. Rakhimov, A.A. Shodiyev, D.M. Olimov. Study of degradation of ethanolamine solutions and their purification from impurities. "Innovations in the oil and gas industry, modern energy and its problems" MATERIALS OF THE 2ND INTERNATIONAL CONFERENCE Tashkent-2021 109-110 p.
7. N.A. Igamkulova, Sh.Sh. Mengliev, T.B. Turaev, Kh.N. Rakhimov, Kh.L. Polatov. Destruction of alkanolamines and their effect on ecology. // "Innovations in the oil and gas industry, modern energy and its problems" Materials of the 2nd international conference Tashkent-2021 . 121-122 p.
8. Rakhimov Ganisher (2023). Increasing the efficiency of heat exchange by changing the construction of a shell and tube heat exchanger. Universum: technical science, (5-8 (110)), 21-24.
doi: https://doi.org/10.5281/zenodo.10358168
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