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ЯО/ - 10.32743/UniTech.2022.103.10.14396
EFFECT OF CHANGE OF POLYETHROPOLIOL AMOUNT ON THE PHYSICAL-MECHANICAL PROPERTIES OF THERMOREACTIVE POLYURETHANE
Asliddin Shodiyev
Doctoral student of the Department of Chemical Technology Navoi State University of Mining and Technology, Republic of Uzbekistan, Navoi E-mail: asliddin. shodiyev. 93@bk. ru
Bakhodir Mukhiddinov
Professor
of the Department of Chemical Technology, Doctor of Chemical Sciences, Navoi State University of Mining and Technology, Republic of Uzbekistan, Navoi
Sharifjon Kiyomov
Senior researcher,
LLC Tashkent Scientific Research Institute of Chemical Technology,
Republic of Uzbekistan, Ibrat
ВЛИЯНИЕ ИЗМЕНЕНИЯ КОЛИЧЕСТВА ПОЛИЭТРОПОЛИОЛА НА ФИЗИКО-МЕХАНИЧЕСКИЕ СВОЙСТВА ТЕРМОРЕАКТИВНОГО ПОЛИУРЕТАНА
Шодиев Аслиддин
докторант
кафедры "Химическая технология " Навоийского государственного горно-технологического университета, Республика Узбекистан, г. Навои
Мухиддинов Баходир Фахриддинович
д-р хим. наук,
проф. кафедры "Химическая технология ", Навоийского государственного горно-технологического университета, Республика Узбекистан, г. Навои
Киёмов Шарифжон Нозимович
ст. науч. сотр,
ООО «Ташкентского научно-исследовательского института химической технологии», Республика Узбекистан, п/о Ибрат
ABSTRACT
This in the article 4 ,4 -methylenediphenyldiisocyanate and polyether polyol based on traditional method thermoreactive polyurethane samples polycondensate received. Polyurethane harvest in doing 100 mass of 4,4- methylenediphenyldiisocyanate 10, 30 and 50 mass per part in parts polyether polyol added. Harvest has been polyurethane of samples equilibrium of elasticity, deformation stress, elongation resistance strength, breaking resilience properties polyether polyol of the amount effect studied.
Библиографическое описание: Shodiyev A., Mukhiddinov B., Kiyomov S. EFFECT OF CHANGE OF POLYETHROPOLIOL AMOUNT ON THE PHYSICAL-MECHANICAL PROPERTIES OF THERMOREACTIVE POLYURETHANE // Universum: технические науки : электрон. научн. журн. 2022. 10(103). URL: https://7universum.com/ru/tech/archive/item/14396
A UNÎVERSUM:
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АННОТАЦИЯ
В статье получен термореактивный полиуретан на основе 4,4-метилендифенилдиизоцианата и полиэфир-полиола по традиционному методу поликонденсации. Образцы полиуретана получены по составам на 100 масс.ч. 4,4-метилендифенил-диизоцианата 10, 30 и 50 масс.ч. полиэфирполиола. Изучено влияние количество полиэфир-полиола на такие свойства полиуретана как: модуль упругости, деформационное напряжение, сопротивление удлинению и сопротивления разрыву.
Keywords: polymer, equilibrium of elasticity, polyester polyol, diisocyanate, elongation resistance strength, breaking strength, deformation stress
Ключевые слова: полимер, модуль упругости, полиэфирполиол, диизоцианат, сопротивление удлинению, прочность на разрыв, деформационное напряжение.
Current at the time metallurgy, mining, agriculture economy, chemistry industry such as different in the fields polymer of materials place is incomparable. This to class incoming polyurethane of materials high elasticity, to be fed endurance, electrical insulation, high deformation such as features at the expense of many applied from polymers is considered. Thermoreactive polyurethanes basically production in the industry application with together metals the place presser materials as mechanical engineering industry is also wide in scope is being used.
This of the polymer viscosity and durability endurance, high elasticity in increasing known one molecular to the mass have hydroxyl keeper polyether polyols polyurethane synthesis is used [1, 2].
Research object
polyurethane of samples equilibrium of elasticity, deformation stress, elongation resistance strength, breaking resilience features polyether polyol (adipin of acid glycols with harvest did complicated ether ) quantity of change effect study is considered.
Methods and materials
The following methods were used in conducting scientific research: GOST 34376.2-2017 "Determining strength properties of polymers"; GOST 4670-2015 "Determination of hardness in plastics"; GOST 567632015 "Determination of polymer composites, resistance to external environment"; such methods were used.
The following substances were used in conducting scientific research: 4,4-methylenediphenyldiisocyanate (GOST 12.1.007-76), Ethylene glycol (XCh) (GOST
Polyurethane samples
9710-2019), density at 20 0 C - 1.113 g/cm 3 , refractive index -1.4315, the boiling point is 197.3 0 C. Butanediol (XCh) (GOST 30333-2007), density at 20 0 C is 1.017 g/cm 3 , boiling point is 235 0 C. Adipine acid ( XCh ) ( GOST 10558-80), melting point - 152 0 C, boiling temperature +265 0 C (100 mm/Hg).
Results and discussion
The studied polyurethane samples were prepared on the basis of 100 parts by weight of 4,4-methylenediphenyldiisocyanate and 10, 30, 50 parts by weight of polyester polyols. The strength limits of the obtained polyurethane sample depend on the amount of polyester polyol depends respectively It was different .
Scientific research at work A component used in the metallurgical industry of parts 4,4-methylenediphenyldiisocyanate on their surfaces and insides to improve performance content covered with polyurethane materials. In order to study the physico-mechanical properties of polyurethane materials, different quantitative parts of polyether polyols added to 4,4-methylenediphenyldiisocyanate were analyzed [3, 4].
The opportunity to mathematically analyze the values of polyurethane samples obtained using physical-mechanical methods such as elasticity balance, breaking resistance index, deformation stress.
4,4-Methylenediphenyldiisocyanate and of polyester polyols from polycondensation yes delete made of (PU-1, PU-2, PU-3) polyurethane of samples mass composition q in house gi in Table-1 given.
Table 1.
mass composition
Sample generating components
No Samples Unity 4,4-Methylenediphenyl diisocyanate Polyether polyol
1 PU-1 weight part 100 10
2 PU-2 weight part 100 30
3 PU-3 weight part 100 50
Above given Physical and mechanical properties of polyurethane samples with different amounts of polyether polyol change is presented in table 2.
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Table 2.
Polyurethane physical and mechanical values of samples
No Test methods Unity PU-1 sample values PU-2 sample values PU-3 sample values
1 Elasticity balance % 70 60 50
2 S is in absorption resistance power kN /m 25 40 60
3 Deformation Voltage MPa 10 6 2
4 The interruption consistency MPa 35 32 16
30
Concentration, С
K- elasticity of polyurethane sample balance indicator, %. C - amount of polyester polyol, %; Figure 1. Samples elasticity balance to the indicator polyether polyol of the amount dependence
Polyetherpolyol increases in the formation of polyurethane sample. The number of bonds between
4,4-methylenediphenyldiisocyanate is ni increase to decrease its elasticity balance take came.
N - polyurethane sample in stretching resistance strength, kN/m , C - polyester polyol amount, % Figure 2. Resistant to wear and tear to the power Dependence of poliefyrpolyol content
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Tensile strength of polymer materials is, in a broad sense, the splitting of objects into parts under the influence of external forces, and irreversible change of their initial shape (plastic deformation). The breaking resistance k index of polymer materials was studied
using [Breaking machine P-0.5] [ 5 , 6]. We can see that with the increase of polyether polyol in the polyurethane samples, the tear resistance index also increased. This is due to the increase in the number of urethane groups and bonds density is increased.
Q - deformation of the polyurethane sample stress, MPa, C - polyether polyol content, % Figure 3. Deformation or stress to i depending on the amount of polyether polyol
Polymeric materials characterizes their elastic and plastic properties, deformation is a mechanical stress expressed by a change in the initial shape of the applied sample [7,8].
Deformation Voltage using the following formula is considered
8 =AL/L0
this on the ground 8- deformation , AL-start' ich length mm, L o -after measurement length mm. Increases plasticity and elasticity property reduction was achieved.
Op - polyurethane set an example, MPa, C - amount of polyether polyol, % Figure 4. Dependence of tensile strength on the amount of polyester polyol
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Values at break for polyurethane samples were considered in the range of pressing pressure from 5 MPa to 40 MPa. Tensile strength of samples (%) is calculated based on the following formula.
£P = ( 1i - I o )*100%/ I o
where sP is the stability limit li after the test of the sample length , mm; lo is the length of the sample before the test , mm [ 8-10 ].
The decrease in tensile strength value was explained by the increase in polyetherpolyol content in polyurethane, the increase in the number of bonds, and the molecular density in the polymer.
Conclusion
Physico-mechanical properties of polyurethane samples formed from polycondensation of 4,4-methylenediphenyldiisocyanate and polyester polyols were studied using different methods. Equilibrium of elasticity, deformation stress, strength limit with increasing content of polyester polyol in polyurethane sample decrease and an increase in the breaking resistance indicator etc. were determined. To this reason 4 ,4 -methylenediphenyldiisocyanate and of polyester polyols i mutually united urethane groups number to increase take is to come.
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2. Yu. S. Kochergin, V.V. Zolotareva, "Iznosostoykost kompozitsionnykh materialov na osnove epokidno-kauchukovykh po-limerov" Vestnik BGTU im. V.G. Shukhova 2017, No. 4-21 ;
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7. GOST 270-75 Rubber. Metod opredeleniya uprugoprochnostnyx svoystv pri rastyazhenii.
8. A.N. Radyuka, N.V. Tsobanova " Materialy dlya detaley niza obvi s polzovaniem v kachestve osnogo komponenta othodov polyurethane " O buv i kojevenno-galantereynye izdeliya, 2019, #1 (3) 41
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