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УДК 543.427.34+549.612 DOI 10.21440/2307-2091-2017-4-52-56
DETECTION OF BERYLLIUM IN OXIDES AND SILICATES BY ELECTRON-PROBE MICROANALYSIS
V. V. Khiller
Определение бериллия в оксидах и силикатах методом рентгеноспектрального микрозондового анализа
В. В. Хиллер
Разработана методика электронно-зондового микроанализа количественного определения содержания бериллия на примере изучения природных минералов (алюмосиликатов и оксидов). Получено количественное содержание бериллия (в совокупности с другими элементами) в изумрудах Мариинского бериллиевого месторождения и зональном мариинските-хризоберилле из хромититов Баженовского офиолитового комплекса. Все анализы минералов выполнены на электронно-зондовом микроанализаторе CAMECA SX 100 с пятью волновыми спектрометрами (ИГГ УрО РАН). Давление в камере образцов составляло 2 • 10-4 Па, в области электронной пушки 2 • 10-6 Па, в волновых спектрометрах — 7 Па. Ускоряющее напряжение 10 кВ, ток поглощенных электронов на цилиндре Фарадея (сила тока) — 100—150 нА. Диаметр пучка электронов, сфокусированных на образце, — 2 мкм, угол отбора рентгеновского излучения — 40°. Спектры получены на волновых спектрометрах с кристаллами-анализаторами TAP (2d = 25,745 A), LPET (2d = 8,75 A), LiF (2d = 4,0267 А) и PC3 (2d = 211,4 А, специализированный кристалл для определения содержания бериллия и бора); измерения всех элементов проводились по Ka-линиям. Предварительно для определения положения аналитического пика и фона с двух сторон, с минимально возможными спектральными наложениями прописывались спектры на волновых спектрометрах. Полученные микрозондовые анализы минералов с количественным определением бериллия хорошо сходятся с имеющимися теоретическими составами бериллов и хризобериллов, что говорит о высокой эффективности разработанной методики. В результате постановки данной методики можно относительно быстро и надежно определять количественное содержание бериллия в природных силикатах и оксидах. Это необходимо для исследователей-геологов при изучении минералогии бериллиевых месторождений.
Ключевые слова: бериллий; хризоберилл; мариинскит; берилл; изумруд; электронно-зондовый микроанализ.
The author developed the technique of electron-probe microanalysis for quantitative determination of beryllium content, providing the example of studying natural minerals (aluminosilicates and oxides). This technique allowed to obtain a quantitative content of beryllium (in combination with other elements) in the emeralds of the Mariinsky beryllium deposit and in zonal mariinskite-chrysoberyl from the chromitites of the Bazhenov ophiolite complex. All analyzes of minerals were performed on a CAMECA SX 100 electron probe microanalyzer with five wave spectrometers (IGG UB RAS). The pressure in the sample chamber was 2 x 10-4 Pa, in the electron gun region — 4 x 10-6 Pa, in wave spectrometers — 7 Pa. Accelerating voltage was 10 kV, the current of absorbed electrons on the Faraday cylinder (beam current) was 100—150 nA. Diameter of the electron beam focused on the sample was 2 |m, the angle of x-ray extraction was 40°. The spectra were obtained on wave spectrometers with TAP crystal analyzers (2d = 25.745 A), LPET (2d = 8.75 A), LiF (2d = 4.0226 A), and PC3 (2d = 211.4 A, a specialized crystal for determining the content of beryllium and boron); the author carried out all the elements measurements along the Ka-lines. To determine position of the analytical peak and the background from two sides with the minimum possible spectral overlap, the author preliminarily recorded spectra on wave spectrometers. The obtained microprobe analyzes of minerals with quantitative determination of beryllium converge well with the available theoretical compositions of beryl and chrysoberyl, which indicates the high efficiency of the developed technique. By using this technique, we can relatively quickly and reliably determine the quantitative content of beryllium in natural silicates and oxides, which is an acute need for geological researchers studying the mineralogy of beryllium deposits.
Keywords: beryllium; chrysoberyl; mariinskite; beryl; emerald; electron-probe mi-croanalysis.
In recent decades, the method of electron-probe microanalysis (EPMA) has been very useful for solving a wide range of issues, including those for which scientists relatively recently considered its application problematic. These include, for example, determination of the elements of the second period of periodic system in minerals [1], related to the development of instrumental and methodological base. When determining the "light" (Be, B, C, N, O, F) elements, difficulties arise [2, 3], as the characteristic X-ray emission lines of these elements are quite wide, they have long-wave X-ray radiation, low peak-to-background ratio, superposition with lines of "heavy" elements, and dependence of the integral intensity of the analytical line on the form of occurrence of the element [4-6]. Currently, the technique of electron-probe microanalysis of content of "ultra-light" beryllium element is not sufficiently developed. This is due to a number of experimental difficulties arising during the analysis: significant influence of the state of chemical bond on the shape and position of maximum of the corresponding element line, significant extent of correction for the matrix effects, necessity of using a special crystal analyzer and inclined spectrometer with ultra-thin polypro-
pylene window, absence of uniform standard samples for the determination of beryllium, etc. Due to the described problems in obtaining accurate analyzes of beryllium content, most publications provide combined or recalculated analyzes of Be-containing minerals. Thus, some researchers normalize the obtained results to a certain amount of oxygen and beryllium [5, 7, etc.], while other scientists determine beryllium using isotopic methods and "add" it to the available microprobe analyzes [8, 9, etc.]. This paper describes the technique of electron-probe microanalysis of beryllium content, on the example of studying natural minerals (aluminosilicates and oxides).
Emerald, a green gemstone, variety of a beryl jewelry is the mineral the author selected in 2008, during a geological excursion held at the All-Russian Scientific Conference "RMS Annual Meeting" on the dumps of the Mariinsky beryllium deposit (near Malysheva settlement, Sverdlovsk region). The author studied flakes and chips of the emerald rims from large beryl individuals composing metacrystals in phlogopite mica (Fig. 1).
All analyzes of emeralds were performed on a CAMECA SX 100 electron probe microanalyzer with five wave spectrometers. Processing ofthe pieces ofmineral consisted ofpreparing them in the form of
Figure 1. Metacrystals of emeralds the author selected at the Mariinsky beryllium deposit. The size of the prismatic crystal is 1 cm in length.
0i--1-1—-1-1-——i—-1-
0,550 0,570 0.590 0.610 0.630 0.650 0.670 0,690 Sin 0
Figure 2. X-ray emission spectra in the range of Be Ka-line for the Ural emerald, mariinskite and standard samples of beryl and Al2SiO5. For the crystal analyzer PC3 (2d = 211.4 A), the recording range of sin © is from 0.55 to 0.70, total 200 points with steps of sin © = 0.00075, the recording time at each point is 2 s.
Table 1. Analytical conditions for measuring characteristic lines for emerald.
Element Standard Element content, wt. % Crystal analyzer Peak position, sin 0 • 105 Left background position, sin 0 • 105 Right background position, sin 0 • 105
Be Beryl 5,03 PC3 61 700 —3230 4000
Na Jadeite 11,28 TAP 46 327 -900 900
Mg Diopside 10,78 TAP 38 478 -900 900
Al Beryl 9,77 TAP 32 448 -750 750
Si Beryl 30,50 TAP 27 738 -500 500
Ca Diopside 18,37 LPET 38 387 -850 850
Ti TiO2 59,95 LPET 31 418 -500 500
V V 99,50 LPET 28 595 -300 300
Cr C2°3 68,42 LPET 26 144 -500 500
Mn Rhodonite 32,85 LiF 52 187 —150 250
Fe Fe2°3 69,94 LiF 48 085 -500 500
Table 2. Results of electrone-probe microanalysis of beryl (emerald).
Analysis Oxide Total
number SiO2 TiO2 V2O3 СГ2°3 Al2O3 MnO FeO MgO CaO BeO Na2°
1 65,45 0,01 0,03 0,02 18,07 0,04 0,39 - 0,01 14,60 0,34 98,95
2 63,49 0,02 0,03 0,49 14,74 0,10 0,61 2,02 0,03 14,40 1,70 97,62
3 63,87 0,01 0,05 0,46 14,46 - 0,55 1,88 0,02 14,60 1,81 97,70
4 63,99 - 0,05 0,45 14,31 0,01 0,67 2,06 0,03 13,90 1,86 97,34
5 63,82 0,01 0,06 0,36 14,35 - 0,56 2,08 0,04 14,40 1,83 97,51
6 63,76 0,01 0,04 0,32 14,79 0,04 0,45 2,05 0,03 14,40 1,69 97,58
7 63,63 0,02 0,07 0,32 14,51 - 0,58 2,03 0,03 14,30 1,72 97,20
Crystallochemical formulas
1 Be3,14 (Al1,91Na0,06Fe0,03)2,00[Si5,86 °18]
2 Be3,10(Al1,56 ; Na0,30Mg0,27Fe0,05Cr0,03) 2,21 |[Si5,69°J
3 Be3,13(Al1,53 Na0,31Mg0,25Fe0,04Cr0,03)2, 1( i[Si5,71°18]
4 Be3,01(Al1,52 :Na0,33Mg0,28Fe0,05Cr0,03)2,21 [Si5,78°18]
5 Be3,09(Al1,52 Na0,32Mg0,28Fe0,04Cr0,03)2, 19 ,[Si5,72°18]
6 Be3,10(Al1,56 Na0,29Mg0,28Fe0,04Cr0,02)2,1S ,[Si5,71°18]
7 Be3,09(Al1,54Na0,30Mgc,27Fe0,04Cr0,02V0,01): 2,18[Si5,73°1 8]
Note: № 1 - standard sample of beryl, № 2-7 - natural emerald.
a polished section, and then spraying with a layer of carbon (a thickness of about 250 A). The accelerating voltage was 10 kV, the beam current was 150 nA, the diameter of the electron beam was 2 ^m, and the angle of x-ray extraction was 40°. The spectra were obtained on wave spectrometers with TAP crystal analyzers (2d = 25.745 A), LPET (2d = 8.75 A), LiF (2d = 4.0226 A), and PC3 (2d = 211.4 A, a specialized crystal for determining the content of beryllium and boron); the measurements of all the elements were carried out along the Ka-lines.
The author determined position of the peak and the background for the both sides of the peak with minimum possible spectral overlaps, Fig. 2 shows X-ray emission spectra on a PC3 crystal analyzer in the range of the Be Ka-line for the Ural emerald and standard samples of beryl and kyanite. One can see that the oxygen lines O Ka5 (sin © = 0.56425), O Ka6 (sin © = 0.67679) and silicon Si Ln (sin © = 0.65805), Si Ll (sin © = 0.66253) do not interfere with the determination of beryllium.
Table 3. Correlation coefficients of the elements in the microanalysis of beryl (emerald).
Oxide BeO Na2O MgO Al2O3 SiO2 CaO TiO2 VO 2 3 Cr O 2 3 MnO FeO
BeO 1
Na2O -0,44 1
MgO -0,44 0,99 1
Al2O3 0,44 -1,00 -0,99 1
SiO2 0,30 -0,94 -0,97 0,94 1
CaO -0,55 0,85 0,88 -0,85 -0,78 1
TiO2 0,37 -0,01 0,07 0,00 -0,30 -0,03 1
V2O3 -0,33 0,68 0,65 -0,71 -0,56 0,70 -0,12 1
C2O3 -0,38 0,91 0,88 -0,90 -0,87 0,61 0,06 0,40 1
MnO 0,09 -0,18 -0,09 0,21 -0,06 -0,23 0,52 -0,76 0,08 1
FeO -0,70 0,75 0,71 -0,75 -0,67 0,55 0,04 0,51 0,81 -0,07 1
Total 0,57 -0,95 -0,96 0,96 0,92 -0,88 -0,04 -0,76 -0,80 0,22 -0,77
When performing the quantitative analysis, the intensity measurement time at the peak (20 s for beryllium, 10 s for the remaining elements) was twice as long as the background measurement time. The standard samples used for calibration and the position of the crystal analyzers during the recording of peak and background intensities (from both sides) of the analytical lines are in Table 1. Spectrometers counters measuring the intensity of the Na, Mg, Al, Si, Ca, Ti, and Be lines had polypropylene windows 0.2 |im thick; spectrometers counters measuring the intensity of V, Cr, Mn, Fe - a beryllium window 25 |im thick; detectors were gas-flow (mixture of Ar and CH4), working in auto-differential mode; the corrections we calculated using the X-PHI model; the oxygen content was determined using the microprobe software, with assumption of stoichiometric composition.
The chemical composition of the emerald in the studied samples varies within narrow limits shown in Table 2. The chromium content, which gives the bright green color to the mineral, is 0.32-0.49 wt. % Cr2O3, there also are significant amounts of sodium impurities (Na2O 1.69-1.86 wt. %), magnesium (MgO about 2 wt. %) and iron (FeO 0.45-0.67 wt. %); variations in the content of BeO from 13.9 to 14.6 wt.% (the detection limit of beryllium is about 1.4 wt.%, standard deviation is 1.3 wt. %, and peak to background ratio is 1.7). The obtained compositions of emeralds are completely satisfactorily recalculated to the crystallochemical formula of beryl (without taking into account the water, which, apparently, is present in the studied samples, within 2-3 wt. %). The author placed all impurity components, according to
the known recommendations [7, 10], in the position of aluminum, while some of the aluminum, in turn, compensates for vacancies in the position of silicon.
The problem of the choice of standards, as for all analytical studies, remains relevant, especially with methodological work in the field of determining light elements. The author used chemical analogs with a similar composition as standards, thus minimizing correction factors. For example, many analysts engaged in the quantitative determination of beryllium in aluminosilicates have faced a serious problem of overlapping silicon and aluminum lines over the beryllium line. We, in the presence of a specialized crystal analyzer PC3, managed to avoid such a situation, i. e. as one can see from Table 3, beryllium has an extremely low correlation with these elements, what in this case means no overlapping lines.
Chrysoberyl-mariinskite. To determine beryllium in a simple natural substance (oxide), the author have chosen a series of minerals of the chrysoberyl group. Recently the author participated in the discovery of a new mineral, Mariinskite, a chrome analogue of chrysoberyl [11]. It is interesting that in the same line of chrysoberyl-mariinskite there is a very rare precious stone - alexandrite, chrome-containing chrysoberyl.
The author decided to study zonal mariinskite (with an intermediate zone of folded chrysoberyl), which forms abundant fine impregnation in hydrothermally altered micaceous chromite ores within the Bazhenovsky ophiolite complex (the surroundings of Asbest
Table 4. Analytical conditions for the measurement of characteristic lines for mariinskite.
Element
Standard
Element content wt. %
Crystal analyzer
Peak position, sin 0 ■ 105
Left background position, sin 0 ■ 105
Right background position, sin 0 ■ 105
Time of measurement on peak, s
Al Ti Fe Cr Be
Corundum Rutile Cr O
2 3
And glass Chrysoberyl
52,92 59,95 21,89 68,42 7,00
TAP LPET LLiF LLiF PC3
32 455 31 421 48 085 56 872 61 629
-700 -300 -500 -500 -8500
700 300 500 500 8620
10 10 10 10 20
9 t# ■
Ъ J
«
-JP
* ж
50 мкм
Figure 4. Maps of intensity distribution of the characteristic X-ray emission of the Al Ka, Cr Ka, Ti Ka and Be Ka lines of the mariinskite grain in the matrix of micaceous chromites.
city, Sverdlovsk region). Grain size of the minerals of the chrysoberyl group does not exceed 1 mm. They have an isometric appearance and high hardness (they protrude strongly from the chromite matrix during polishing). The minerals color is black in mass, emerald-green in clearance (Fig. 3). In addition to chromite, in association with them one can note mica (alumoseladonite, fluorophlogopite and muscovite), chromium tourmaline, fluorapatite and eskolaite [12].
The conditions for measuring the oxides of the BeAl2O4-BeCr2O4 series have been partially explained in previous papers [13, 14, etc.]. All analyzes of oxides were also performed on a CAMECA SX 100 electron probe micro analyzer. The pressure in the sample chamber was 2 • 10-4 Pa, in the electron gun region 4 • 10-6 Pa, in wave spectrometers - 7 Pa. Accelerating voltage was 10 kV, current of absorbed electrons on the Faraday cylinder - 100 nA. The diameter of the beam of electrons focused on the sample was 2 |im. Preliminarily, to determine the position (sin © • 105) of the peak and the background from both sides of the analytical peak, with the minimum possible spectral overlap, the author recorded spectra on wave spectrometers with TAP, LPET, LLiF and PC3 (determination of beryllium and boron) crystal analyzers. Fig. 2 shows X-ray emission spectra on the PC3 crystal ana-
lyzer in the range of Be Ka-line for mariinskite and standard samples of beryl and kyanite. Measurements of all elements for the analysis of the mineral were along the Ka-lines, with minimal spectral overlap during determination of the positions of peak and background levels. The author sputtered standard and test samples with carbon. The sputtering thickness on the standards was "industrial", i. e. according to the passport 250 A, the sputtering thickness on the section with the studied mineral was determined indirectly, by the color of the copper plate (a red-orange color identical to the sputtering on standards, also mounted on a copper shim). Standard samples: chrysoberyl - BeAl2O4 from Brazil, corundum - Al2O3 (synthetic, 99.9999 %), chromium oxide -Cr2O3 (synthetic, > 99.99 %), rutile - TiO2 (synthetic, 99.999 %), And glass - synthetic glass of andradite composition. Counter was gas-flow (gas mixture Ar-CH4), detector mode was auto-differential. One can see the conditions for measuring the lines in Table 4, with the corrections calculated according to the X-PHI model (which is better for low voltage). Based on the stoichiometry of the mineral, a microprobe software also automatically calculated oxygen level.
Chemical composition of the minerals of the chrysoberyl-mariinskite series in the studied crystals varies from aluminous
Table 5. Results of electron-probe microanalysis of mariinskite chrysoberyl.
Mineral Oxide Total
BeO Al2O3 -ТЮ2 Cr O 2 3 Fe2O3
i7,i9 29,73 0,i2 52,99 0,i3 i00,i6
i5,98 i7,78 0,8i 65,39 0,i9 i00,i5
Mariinskite i6,05 25,79 0,i2 57,22 0,4i 99,60
i4,8i i9,0i 0,77 63,98 0,26 98,83
i7,i0 28,59 0,i2 54,04 0,38 i00,23
i7,36 37,53 0,36 44,30 0,38 99,93
Chrysoberyl i6,55 i7,78 33 85 0,30 0,i4 47.20 48.21 0,i9 0,40 99,76 i00,37
i7,28 33,03 0,22 48,68 0,20 99,42
Crystallochemical formulas
Mariinskite
Be1,o5(Cr1,oeA|o,89)1,9504 Bei,03(Cri,39Al0,56T'0,02)1,97O4
Bei,oi(Cri,l9A|o,8o)l,9904
Be0,98(Cri,38Al0,62Ti0,02)2,02°4 Bei,05(Cri,09Al0,86)l,95O4
Chrysoberyl
Bei,03(Ali,09Cr0,87T10,0i)i,97O4 Bei,00(Ali,05Cr0,94T10,0i)2,00O4 Bei,06(Al0,99Cr0,95)i,94O4 Bei,05(Al0,98Cr0,97)i,95O4
BeCr2O4 to chromic BeAl2O4 (Table 5); in their elemental mapping (Fig. 4), the author established a distinct zoning in distribution of aluminum (Al2O3 17.8-37.5 wt. %), chromium (Cr2O3 44.3-65.4 wt. %) and iron (FeO 1.2-2.6 wt. %). The most aluminous zones in the form of chrysoberyl create intermediate regions in BeCr2O4 individuals, with variations in the BeO content from 16.4 to 22.1 wt. % (the limit of beryllium detection of is about 1 wt. %, peak to background ratio is about 2.8).
In general, the obtained microprobe analyzes of minerals with quantitative determination of beryllium coincide with the available theoretical compositions of beryls and chrysoberyls, which indicates the high efficiency of the developed technique. As a result using this technique, we can relatively quickly and reliably determine quantitative content of beryllium in natural silicates and oxides, which is an acute need for geological researchers studying the mineralogy of beryllium deposits. For example, this technique significantly facilitated the passage of our application for mariinskite in the commission for new minerals of the International Mineralogical Association.
Thereby, the author developed the technique of electron-probe microanalysis of beryllium content on example of studying natural minerals (aluminosilicates and oxides). The technique allowed to
obtain a quantitative content of beryllium (in combination with other elements) in the emeralds of the Mariinsky beryllium deposit and in the zonal mariinskite - chrysoberyl from the chromitites of the Bazhenov ophiolite complex.
REFERENCES
1. Lavrent'ev Yu. G., Karmanova N. G. 2012, Sed'maya Vserossiyskaya konferentsiya po rentgenospektral'nomu analizu [Seventh All-Russian Conference on X-ray Spectroscopy]. Zhurnal analiticheskoy khimii [Journal of Analytical Chemistry], vol. 67, no. 6, pp. 669-671.
2. Aleksandrov S. M., Troneva M. A. 2011, Elektronno-zondovyy mikroanaliz en-dogennykh boratov margantsa iz skarnovykh mestorozhdeniy Yaponii [Electron probe microanalysis of endogenous manganese borates from Japanese skarn deposits]. VII Vserossiyskaya konferentsiya po rentgenospektral'nomu analizu. Tezisy dokladov [All-Russian Conference on X-ray Spectroscopy. Theses of reports], Novosibirsk, p. 47.
3. Raudsepp M. 1995, Recent advances in the electron-probe microanalysis of minerals for the light elements. Canadian Mineralogist, vol. 33, pp. 203-218.
4. Viryus A. A. 2010, Lokal'nyy rentgenospektral'nyy analiz geologicheskikh ob'ektov [Local X-ray spectral analysis of geological objects]. Materialy VI Mezh-dunarodnoy Shkoly po Naukam o Zemle imeni professora L. L. Perchuka [Materials of the International School for Earth Sciences named after prof. Perchuk L. L.], Odessa, p. 29-31.
5. Kulikova I. M. 1995, Rentgenospektral'nyy mikrozondovyyanaliz soderzhaniya bora v razlichnykh mineralakh. Metodicheskie rekomendatsii. VIMS [X-ray spectral microprobe analysis of boron content in various minerals. Guidelines. All-Russian Institute of Mineral Raw Materials], Moscow, 18 p.
6. Troneva M. A., Kononkova N. N., Aleksandrov S. M. 2006, Rentgenospektral'nyy analiz boratov na primere lyudvigitov i vonsenitov [X-ray spectral analysis of borates on the example of ludwigites and vonsenites]. Tezisy dokladov V Vserossiyskoy konferentsii po rentgenospektral'nomu analizu [Abstracts of the All-Russian Conference on X-ray Spectroscopy], Irkutsk, 80.
7. Groat L. A., Giuliani G., Marshall D. D., Turner D. 2008, Emerald deposits and occurrences: A review. Ore Geology Reviews, vol. 34, pp. 87-112.
8. Grice J. D., Rowe R., Poirier G. 2009, Bussyite-(Ce), a new beryllium silicate mineral species from Mont Saint-Hilaire, Quebec. Canadian Mineralogist, vol. 47, pp. 193-204.
9. Pekov I. V., Zubkova N. V., Chukanov N. V., Agakhanov A. A., Belakovskiy D. I., Hor-vath L., Filinchuk Ya. E., Gobechiya E. R., Pushcharovsky D. Yu., Rabadanov M. K. 2008, Niveolanite, the first natural beryllium carbonate, a new mineral species from Mont Saint-Hilaire, Quebec, Canada. Canadian Mineralogist, vol. 46, pp. 1343-1354.
10. Artioli G., Rinaldi R., Stahl K., Zanazzi P. F. 1993, Structure refinements of beryl by single-crystal neutron and X-ray diffraction. American Mineralogist, vol. 78, pp. 762-768.
11. Pautov L. A., Popov M. P., Erokhin Yu. V., Khiller V. V., Karpenko V. Yu. 2013, Mariinskite, BeCr2O4, a new mineral, chromium analog of chrysoberyl. Geology of Ore Deposits, vol. 55, no. 8, pp. 648-662.
12. Erokhin Yu. V., Khiller V. V., Zoloev K. K., Popov M. P., Grigor'ev V. V. 2014, Mariinskite from the Bazhenovskii ophiolite complex: the second finds in the World. Doklady Earth Sciences, vol. 455, part 2, pp. 408-410.
13. Khiller V. V., Erokhin Yu. V. 2011, Mikrozondovoe opredelenie berilliya vmineralakh ryada BeAl2O4-BeCr2O4 [Microprobe determination of beryllium in minerals of the series BeAl2O4-BeCr2O4]. VII Vserossiyskaya konferentsiya po rentgenospektral'nomu analizu. Tezisy dokladov [All-Russian Conference on X-ray Spectros-copy. Theses of reports], Novosibirsk, p. 80.
14. Khiller V. V., Erokhin Yu. V. 2012, Opredeleniesoderzhaniya berilliya metodom rentgeno-spektral'nogo elektronno-zondovogo mikroanaliza [Determination of beryllium content by X-ray spectral electron probe microanalysis]. Materialy Vserossiyskoy konferentsii po analiticheskoy spektroskopii [Materials of the All-Russian Conference on Analytical Spectroscopy], Krasnodar, pp. 175.
Вера Витальевна Хиллер
hilvervit@mail.ru
Институт геологии и геохимии
им. академика А. Н. Заварицкого УрО РАН
Россия, Екатеринбург, ул. Академика Вонсовского, 15
Vera Vital'evna Khiller
hilvervit@mail.ru
Zavaritsky Institute of Geology and Geochemistry of the Ural Branch of the Russian Academy of Sciences Ekaterinburg, Russia
