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4Colloidal synthesis of halide perovskite microwires for photonics
and optoelectronics
A. Pushkarev
Faculty of Physics, ITMO University, Kronverksky Pr. 49, 197101 St. Petersburg, Russia [email protected]. ru
Over the last decade halide perovskite microwires have emerged as a platform for numerous photonic and optoelectronic applications including solar cells, lasers, optical gas sensors, photodetectors, electroluminescent photodetectors, integrated photonic devices, etc. [1-6] Colloidal synthesis of microwires have many advantages over frequently employed chemical vapor deposition (CVD) and substrate-assisted solution growth. Among them there are easy doping of perovskite crystal lattice by transition metal ions that results in bandgap tuning and change in conductivity, along with simplicity of microwires integration with various nanostructures and electrodes by using drop-casting to produce complex devices. However, there is the only report devoted to colloidal perovskite microwires so far [7]. In my talk, I will present a novel colloidal synthesis of all-inorganic perovskite microwires, laser action in them, as well as optoelectronic devices, in particular single-crystal-based gas sensor and memristor.
This work was supported by the Russian Science Foundation (project no. 24-73-10072).
[1] J.-H. Im, J. Luo, M. Franckevicius, N. Pellet, P. Gao, T. Moehl, S. Zakeeruddin, M. Nazeeruddin, M. Grätzel, N.-G. Park, Nanowire Perovskite Solar Cell, Nano Lett., 15, 2120-2126, (2015).
[2] A. Zhizhchenko, A. Cherepakhin, M. Masharin, A. Pushkarev, S. Kulinich, A. Kuchmizhak, S. Makarov, Directional Lasing from Nanopatterned Halide Perovskite Nanowire, Nano Lett., 21, 10019-10025, (2021).
[3] D. Markina, S. Anoshkin, M. Masharin, S. Khubezhov, I. Tzibizov, D. Dolgintsev, I. Terterov, S. Makarov, A. Pushkarev, Perovskite Nanowire Laser for Hydrogen Chloride Gas Sensing, ACS Nano, 17, 1570-1582, (2023).
[4] Q. Ye, J. Zhang, P. Guo, H. Fan, D. Shchukin, B. Wei, H. Wang, Wet-Chemical Synthesis of Surface-Passivated Halide Perovskite Microwires for Improved Optoelectronic Performance and Stability, ACS Appl. Mater. Interfaces, 10, 43850-43856, (2018).
[5] A. Marunchenko, V. Kondratiev, A. Pushkarev, S. Khubezhov, M. Baranov, A. Nasibulin, S. Makarov, Mixed Ionic-Electronic Conduction Enables Halide Perovskite Electroluminescent Photodetector, Laser Photonics Rev., 17, 2300141, (2023).
[6] Q. Han, J. Wang, S. Tian, S. Hu, X. Wu, R. Bai, H. Zhao, D. Zhang, Q. Sun, L. Ji, Inorganic Perovskite-Based Active Multifunctional Integrated Photonic Devices, Nat. Commun., 15, 1536, (2024).
[7] W. Zhang, L. Peng, J. Liu, A. Tang, J.-S. Hu, J. Yao, Y. Zhao, Controlling the Cavity Structures of Two-Photon-Pumped Perovskite Microlasers, Adv. Mater., 28, 4040-4046, (2016).
